488151-78-6

Basic information

• Product Name: Ethanone, 1-[2-[[3-[(1,1-dimethylethyl)dimethylsilyl]-2-propynyl]oxy]-3-methylphenyl] -
• CAS NO: 488151-78-6
• Molecular Formula: C18H26O2Si
• Molecular Weight: 302.489
• Mol File: 488151-78-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ethanone, 1-[2-[[3-[(1,1-dimethylethyl)dimethylsilyl]-2-propynyl]oxy]-3-methylphenyl] -(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-[2-[[3-[(1,1-dimethylethyl)dimethylsilyl]-2-propynyl]oxy]-3-methylphenyl] -(488151-78-6)
• EPA Substance Registry System: Ethanone, 1-[2-[[3-[(1,1-dimethylethyl)dimethylsilyl]-2-propynyl]oxy]-3-methylphenyl] -(488151-78-6)

Safety Data

• Hazardous Substances Data: 488151-78-6(Hazardous Substances Data)

Upstream product

• 699-91-2 2-acetyl-6-methylphenol 
• 120789-51-7 3-tert-butyldimethylsilylpropargyl alcohol 

Downstream Products

• 488150-54-5 methyl 3-[2-(3-tert-butyldimethylsilyl-2-propynyloxy)-3-methylphenyl]-2-diazo-3-oxopropionate 
• 488150-79-4 methyl 3-[2-(3-tert-butyldimethylsilyl-2-propynyloxy)-3-methylphenyl]-3-oxopropionate 

Relevant articles and documents

Enantioselective tandem formation and [2,3]-sigmatropic rearrangement of cyclic propargylic oxonium ylides catalyzed by dirhodium(II) tetrakis[N-phthaloyl-(S)-tert-leucinate]

This paper describes the first examples of catalyst-dependent asymmetric induction in the periselective [2,3]-sigmatropic rearrangement of propargylic oxonium ylides generated by catalytic diazo decomposition. Catalysis of α-diazo-β-keto esters 4a-g using