4933-59-9

Basic information

• Product Name: Cyclohexene, 1-bromo-2,3,3,4,4,5,5,6,6-nonafluoro-
• CAS NO: 4933-59-9
• Molecular Formula: C6BrF9
• Molecular Weight: 322.956
• Mol File: 4933-59-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Cyclohexene, 1-bromo-2,3,3,4,4,5,5,6,6-nonafluoro-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexene, 1-bromo-2,3,3,4,4,5,5,6,6-nonafluoro-(4933-59-9)
• EPA Substance Registry System: Cyclohexene, 1-bromo-2,3,3,4,4,5,5,6,6-nonafluoro-(4933-59-9)

Safety Data

• Hazardous Substances Data: 4933-59-9(Hazardous Substances Data)

Upstream product

• 638-84-6 1,2-dibromo-1H-nonafluoro-cyclohexane 
• 355-75-9 decafluorocyclohex-1-ene 
• 777-97-9 2,3,3,4,4,5,5,6,6-nonafluorocyclohexene 
• 81607-30-9 2,3,4,5,6-pentafluorophenyldifluorobromane 

Downstream Products

• 5492-89-7 1-pentafluorophenyl nonafluoro cyclohexene 
• 10575-60-7 perfluoro-3,3',4,4',5,5',6,6'-octahydrobiphenyl 
• 10575-65-2 1-phenylnonafluorocyclohexene 

Relevant articles and documents

Bis(perfluoroorganyl)bromonium salts [(RF)2Br]Y (RF = aryl, alkenyl, and alkynyl)

Bromonium salts [(RF)2Br]Y with perfluorinated groups RFC6F5, CF3CFCF, C 2F5CFCF, and CF3C≡C were isolated from reactions of BrF3 with RFBF2 in weakly coordinating solvents (wcs) like CF3CH2CHF2 (PFP) or CF3CH2CF2CH3 (PFB) in 30-90% yields. C6F5BF2 formed independent of the stoichiometry only [(C6F5)2Br][BF 4]. 1:2 reactions of BrF3 and silanes C6F 5SiY3 (Y = F, Me) ended with different products - C 6F5BrF2 or [(C6F5) 2Br][SiF5] - as pure individuals, depending on Y and on the reaction temperature (Y = F). With C6F5SiF3 at ≥-30 °C [(C6F5)2Br][SiF5] resulted in 92% yield whereas the reaction with less Lewis acidic C 6F5SiMe3 only led to C6F 5BrF2 (58%). The interaction of K[C6F 5BF3] with BrF3 or [BrF2][SbF 6] in anhydrous HF gave [(C6F5) 2Br][SbF6]. Attempts to obtain a bis(perfluoroalkyl) bromonium salt by reactions of C6F13BF2 with BrF3 or of K[C6F13BF3] with [BrF2][SbF6] failed. The 3:2 reactions of BrF3 with (C6F5)3B in CH2Cl2 gave [(C6F5)2Br][(C6F 5)nBF4-n] salts (n = 0-3). The mixture of anions could be converted to pure [BF4]- salts by treatment with BF3·base.

The first hydrogen containing (polyfluorocycloalken-1-yl)xenon(II) salts

(2-H-Hexafluoro-1,4-cyclohexadien-1-yl)xenon(II) and (2-H-octafluorocyclohexen-1-yl)xenon(II) hexafluoroarsenates and tetrafluoroborates were obtained together with their perfluorinated analogues on reacting the corresponding (2,3,4,5-tetrarluorophenyl)xenon(II) salts with XeF2 in anhydrous HF (aHF). The fluorinated (cyclohexen-1-yl)xenon(II) cations react with bromide and iodide anions in MeCN and aHF under alkenylation of the halide anions.