494227-35-9

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Product Name: (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE
Synonyms: MANDYPHOS SL-M002-1;(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE;(S,S)-(+)-2,2'-BIS[(R)-(N,N-DIMETHYLAMINO)(PHENYL)METHYL]-1,1'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE;(R,R)-1,1'-BIS[(R)-ALPHA-(DIMETHYLAMINO)PHENYLMETHYL]-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE;(R,R)-1,1#-Bis[-(dimethylamino)benzyl]-(S,S)-2,2#-bis(dicyc;(S,S)-(+)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(dicyclohexylphosphino)ferrocene,min.97%;(r,r)-1,1'-bis[(r)-α-(dimethylamino)phenylmethyl]-2,2'-bis(dicyclohexylphosphino)ferrocene (acc to cas);(αr,αr)-1,1'-bis[α-(dimethylamino)benzyl]-(s,s)-2,2'-bis(dicyclohexylphosphino)ferrocene
CAS NO:494227-35-9
Molecular Formula: C52H74FeN2P2 10*
Molecular Weight: 844.95
EINECS: N/A
Product Categories: Chiral Phosphine;Ferrocene Series;Mandyphos Series
Mol File: 494227-35-9.mol
Article Data: 0

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: orange-red/solid
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
Stability: store cold
CAS DataBase Reference: (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE(CAS DataBase Reference)
NIST Chemistry Reference: (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE(494227-35-9)
EPA Substance Registry System: (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE(494227-35-9)

Safety Data

Hazard Codes: N/A
Statements: N/A
Safety Statements: N/A
WGK Germany: 3
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 494227-35-9(Hazardous Substances Data)

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Factory Price OLED 99% 494227-35-9 (S,S)-(+)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(dicyclohexylphosphino) ferrocene Manufacturer
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(1R,1'R)-1,1'-Bis(dicyclohexylphosphino)-2,2'-bis[(R)-(dimethylamino)phenylmethyl]ferrocene CAS 494227-35-9 In stock
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1-(dicyclohexylphosphanyl)-2-[(S)-(dimethylamino)(phenyl)methyl]cyclopentane-1,2,3,4,5-pentayl - iron (2:1)
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(S,S)-(+)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(dicyclohexylphosphino) ferrocene
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(S,S)-(+)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(dicyclohexylphosphino) ferrocene
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(1R,1'R)-1,1'-Bis(dicyclohexylphosphino)-2,2'-bis[(R)-(dimethylamino)phenylmethyl]ferrocene
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Suzhou Health Chemicals Co., Ltd.
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(S,S)-(+)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(dicyclohexylphosphino) ferrocene Cas no.494227-35-9 98%
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(SP,S'P)-1,1'-Bis(dicyclohexylphosphino)-2,2'-bis[(R)-alpha-(dimethylamino)benzyl]ferrocene
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494227-35-9 Usage

Reaction

Ligand for a copper-catalyzed domino conjugated reduction/aldol reaction of methyl acrylate with various alkyl aryl ketones. Ligand for gold catalyzed Phenol synthesis from furyldialkyne Ligand for asymmetric palladium-catalyzed cross-coupling of aryl triflates with [(η6-benzylamine)Cr(CO)3]

Chemical Properties

Orange powder

General Description

sold in collaboration with Solvias AG

Check Digit Verification of cas no

The CAS Registry Mumber 494227-35-9 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 4,9,4,2,2 and 7 respectively; the second part has 2 digits, 3 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 494227-35:
(8*4)+(7*9)+(6*4)+(5*2)+(4*2)+(3*7)+(2*3)+(1*5)=169
169 % 10 = 9
So 494227-35-9 is a valid CAS Registry Number.

InChI:InChI=1/2C26H37NP.Fe/c2*1-27(2)26(21-13-6-3-7-14-21)24-19-12-20-25(24)28(22-15-8-4-9-16-22)23-17-10-5-11-18-23;/h2*3,6-7,12-14,19-20,22-23,26H,4-5,8-11,15-18H2,1-2H3;/t2*26-;/m11./s1

494227-35-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name	(S,S)-(+)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(dicyclohexylphosphino) ferrocene, min. 97%

1.2 Other means of identification

Product number	-
Other names	MANDYPHOS SL-M002-1

1.3 Recommended use of the chemical and restrictions on use

Identified uses	For industry use only.
Uses advised against	no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number	-
Service hours	Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

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