49539-99-3

Basic information

• Product Name: mercuric triflate
• CAS NO: 49539-99-3
• Molecular Weight: 498.731
• Mol File: 49539-99-3.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: mercuric triflate(CAS DataBase Reference)
• NIST Chemistry Reference: mercuric triflate(49539-99-3)
• EPA Substance Registry System: mercuric triflate(49539-99-3)

Safety Data

• Hazardous Substances Data: 49539-99-3(Hazardous Substances Data)

Upstream product

• 1493-13-6 trifluorormethanesulfonic acid 
• 12653-71-3 mercury(II) oxide 
• 7722-84-1 dihydrogen peroxide 
• 21259-75-6 mercury bis(trifluoromethanethiolate) 
• 748084-55-1 mercuric carbonate 
• 358-23-6 trifluoromethylsulfonic anhydride 

Downstream Products

• 75-44-5 phosgene 
• 358-23-6 trifluoromethylsulfonic anhydride 
• 1357461-91-6 Hg(CF₃SO₃)2(C₅H₄NCH₂PO(C₆H₅)2)2 
• 1357461-89-2 Hg(OTf)2(2-(diphenylphosphinomethyl)pyridine)2 

Relevant articles and documents

Aryl-Allene Cyclization via a Hg(OTf)2-Catalytic Pathway

Hg(OTf)2-catalyzed aryl-allene cyclization accompanied by formation of a quaternary carbon center has been realized. Deuterium-labeling experiments and computational modeling were used to propose a novel catalytic pathway involving direct H-transfer from the aromatic ring to the vinyl mercury moiety followed by mercury 1,2-migration.

M -C2B10H11HgCl/AgOTf-Catalyzed Reaction for Reductive Deoxygenation

A m -C2B10H11HgCl/AgOTf-catalyzed reaction of allyl silyl ethers with N -Boc- N ′-tosylhydrazine has been developed. Under mild conditions, the resulting allyl hydrazine products were transformed into naked alkenes in good yield. Furthermore, the used m -C2B10H11HgCl could be recovered quantitatively.