50337-75-2 Usage
Chemical structure
1-(tert-butoxy)naphthalene consists of a naphthalene core with a tert-butoxy group attached to it.
Functional groups
The compound has a naphthalene ring system and a tert-butoxy group.
Solvent properties
It is commonly used as a solvent due to its low toxicity and high solvency power.
Steric hindrance
The tert-butoxy group provides steric hindrance, making the compound more stable and less reactive.
Applications
It is often used in organic synthesis and as a component of specialty coatings, adhesives, and sealants.
Safety precautions
It is important to handle 1-(tert-butoxy)naphthalene with caution, as it can be harmful if it comes into contact with skin or if it is inhaled.
Environmental impact
It has the potential to cause environmental harm, so proper disposal and handling procedures should be followed.
Physical state
The compound is likely to be a liquid at room temperature, as it is a relatively non-polar molecule with a large molecular size.
Boiling point
The boiling point of 1-(tert-butoxy)naphthalene is not provided in the material, but it can be inferred that it would be higher than that of naphthalene due to the additional tert-butoxy group.
Density
The density of 1-(tert-butoxy)naphthalene is not provided in the material, but it can be expected to be higher than that of naphthalene due to the presence of the tert-butoxy group.
Viscosity
The viscosity of 1-(tert-butoxy)naphthalene is not provided in the material, but it can be expected to be higher than that of naphthalene due to the increased steric hindrance from the tert-butoxy group.
Flashpoint
The flashpoint of 1-(tert-butoxy)naphthalene is not provided in the material, but it can be expected to be higher than that of naphthalene due to the presence of the tert-butoxy group, which may reduce the compound's flammability.
Chemical stability
The compound is more stable than naphthalene due to the presence of the tert-butoxy group, which provides steric hindrance and reduces reactivity.
Reactivity
The reactivity of 1-(tert-butoxy)naphthalene is reduced compared to naphthalene due to the steric hindrance provided by the tert-butoxy group.
Compatibility
The compound is likely to be compatible with a range of organic solvents and materials, as it is used in organic synthesis and as a component of specialty coatings, adhesives, and sealants.
Check Digit Verification of cas no
The CAS Registry Mumber 50337-75-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,0,3,3 and 7 respectively; the second part has 2 digits, 7 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 50337-75:
(7*5)+(6*0)+(5*3)+(4*3)+(3*7)+(2*7)+(1*5)=102
102 % 10 = 2
So 50337-75-2 is a valid CAS Registry Number.
InChI:InChI=1/C14H16O/c1-14(2,3)15-13-10-6-8-11-7-4-5-9-12(11)13/h4-10H,1-3H3
50337-75-2Relevant articles and documents
Bradshaw,Hales
, p. 318 (1971)
A convenient synthesis of tert-butyl ethers under microwave condition
Mahammed,Keshava Murthy,Mohana Raju
, p. 575 - 578 (2008/09/20)
Synthesis of tert-butyl ethers from various alcohols and substituted phenols can be achieved using tert-butyl bromide in the presence of basic lead carbonate as a catalyst under microwave irradiation in absence of solvent. The catalyst is easily recovered via filtration and reused up to three times without appreciable loss of activity.
Alcohols and di-tert-butyl dicarbonate: How the nature of the Lewis acid catalyst may address the reaction to the synthesis of tert-butyl ethers
Bartoli, Giuseppe,Bosco, Marcella,Carlone, Armando,Dalpozzo, Renato,Locatelli, Manuela,Melchiorre, Paolo,Sambri, Letizia
, p. 9580 - 9588 (2007/10/03)
The reaction between alcohols and Boc2O leads to the formation of ferf-butyl ethers and/or Boc-alcohols, depending on the nature of the Lewis acid catalyst. Product distribution is mainly tuned by the anionic part of the salt. Perchlorates and Inflates, anions with highly delocalized negative charge, give prevalent or exclusive ether formation. On the other hand, Boc alcohols are the main or exclusive products with un-delocalized isopropoxide or low-delocalized acetate ions. The metal ion influences only the reaction rate, roughly following standard parameters for calculating Lewis acidity. A reaction mechanism is supposed, and a series of experimental evidences is reported to support it. These studies allowed us to conclude that, to synthesize tert-butyl ethers, in reactions involving aliphatic alcohols, Mg(ClO4) 2 or Al(ClO4)3 represents the best compromise between costs and efficiency of the reaction, while, in reactions involving phenols, Sc(OTf)3 is the best choice, since aromatic tert-butyl ethers are not stable in the presence of perchlorates.