503560-10-9

Basic information

• Product Name: N-[2-(tert-butyl-dimethyl-silanyloxy)-1-formyl-ethyl]-benzamide
• Synonyms: N-[2-(tert-butyl-dimethyl-silanyloxy)-1-formyl-ethyl]-benzamide
• CAS NO: 503560-10-9
• Molecular Weight: 307.465
• Mol File: 503560-10-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: N-[2-(tert-butyl-dimethyl-silanyloxy)-1-formyl-ethyl]-benzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-[2-(tert-butyl-dimethyl-silanyloxy)-1-formyl-ethyl]-benzamide(503560-10-9)
• EPA Substance Registry System: N-[2-(tert-butyl-dimethyl-silanyloxy)-1-formyl-ethyl]-benzamide(503560-10-9)

Safety Data

• Hazardous Substances Data: 503560-10-9(Hazardous Substances Data)

Downstream Products

• 482315-17-3 6-[1-(tert-butyl-dimethyl-silanyloxy)-9-(2-hexyl-[1,3]dioxolan-2-yl)-non-2-enyl]-3a-methyl-2-phenyl-6,6a-dihydro-3aH-furo[3,4-d]oxazol-4-one 
• 482315-10-6 6-[1-(tert-butyl-dimethyl-silanyloxy)-3-iodo-allyl]-3a-methyl-2-phenyl-6,6a-dihydro-3aH-furo[3,4-d]oxazol-4-one 
• 1027571-48-7 (4S,5R)-5-Formyl-4-methyl-2-phenyl-4,5-dihydro-oxazole-4-carboxylic acid methyl ester 
• 503560-05-2 3-((4S,trans)-4,5-dihydro-4-methyl-2-phenyloxazol-5-yl)-heptadecan-3-one-16-ethylenacetal 
• 503560-06-3 3-((4S,trans)-4,5-dihydro-4-(tert-butyldimethylsilanyloxymethyl)-2-phenyloxazol-5-yl)-N-methoxy-N-methyl-propionamide 
• 503560-11-0 3-[(4S,5S)-4-(tert-Butyl-dimethyl-silanyloxymethyl)-2-phenyl-4,5-dihydro-oxazol-5-yl]-propionic acid 
• 503560-08-5 3-((4S,trans)-4,5-dihydro-4-(tert-butyldimethylsilanyloxymethyl)-2-phenyloxazol-5-yl)-propionic acid methyl ester 
• 497227-92-6 (3aS,6R,6aR)-6-((E)-3-Iodo-allyl)-3a-methoxymethoxymethyl-2-phenyl-6,6a-dihydro-3aH-furo[3,4-d]oxazol-4-one 
• 503560-07-4 (2E)-3-((4S,trans)-4,5-dihydro-4-(tert-butyldimethylsilanyloxymethyl)-2-phenyloxazol-5-yl)-acrylic acid methyl ester 
• 503560-13-2 3-(4-iodomethyl-2-phenyl-4,5-dihydro-oxazol-5-yl)-N-methoxy-N-methyl-propionamide 
• 497227-90-4 (4S,5S)-4-Methoxymethoxymethyl-2-phenyl-5-vinyl-4,5-dihydro-oxazole-4-carboxylic acid methyl ester 
• 503560-12-1 3-(4-hydroxymethyl-2-phenyl-4,5-dihydro-oxazol-5-yl)-N-methoxy-N-methyl-propionamide 
• 1027989-75-8 (4S,5R)-5-Formyl-4-methoxymethoxymethyl-2-phenyl-4,5-dihydro-oxazole-4-carboxylic acid methyl ester 

Relevant articles and documents

Total synthesis of sphingofungin F.

[reaction: see text] A concise, stereocontrolled synthesis of sphingofungin F was achieved. Key features involve diastereoselective oxazoline formation catalyzed by palladium(0), MgBr(2)-promoted gamma-alkoxy allylic stannane addition, and palladium(0)-ca

Stereoselective synthesis of (+)-spectaline

Our synthesis of (+)-spectaline revealed that the methodology involving diastereoselective palladium(0)-catalyzed oxazoline formation and intramolecular reductive amination by catalytic hydrogenation of an oxazoline is an effective method for the asymmetric synthesis of natural products possessing complex functionalized piperidine cores.