505069-65-8

Basic information

• Product Name: trans, cis-[RuCl₂(DMSO-S)2(H₂NCH₂CH₂P(O)Ph₂-N,O)]
• CAS NO: 505069-65-8
• Molecular Weight: 573.507
• Mol File: 505069-65-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trans, cis-[RuCl₂(DMSO-S)2(H₂NCH₂CH₂P(O)Ph₂-N,O)](CAS DataBase Reference)
• NIST Chemistry Reference: trans, cis-[RuCl₂(DMSO-S)2(H₂NCH₂CH₂P(O)Ph₂-N,O)](505069-65-8)
• EPA Substance Registry System: trans, cis-[RuCl₂(DMSO-S)2(H₂NCH₂CH₂P(O)Ph₂-N,O)](505069-65-8)

Safety Data

• Hazardous Substances Data: 505069-65-8(Hazardous Substances Data)

Upstream product

• 72904-47-3 trans-dichlorotetrakis(dimethyl sulfoxide)ruthenium(II) 
• 4848-43-5 (2-aminoethyl)diphenylphosphane 

Relevant articles and documents

Chelate ring-opening aminophosphine complexes of ruthenium(II)

The preparations and X-ray crystal structures of the Ru(II) aminophosphine complexes trans, cis-[RuCl2(H(Bz)NCH2CH2PPh2-N,P) 2] (1), trans, cis-[RuCl2(H2NCH2CH2PPh 2-N,P)2] (3) and [(η6-C6H6)Ru(PPh2CH 2CH2NMe2-N,P)Cl][PF6] (5) are described. Complexes 1 and 3 are octahedral and contain a marked distortion of the Cl-Ru-Cl axis from linearity. Complex 3 undergoes facile chelate ring-opening in DMSO and CH3CN solutions to give complexes containing one chelated aminophosphine ligand and one pendant ligand coordinated only through P. The X-ray structure of trans, cis-[RuCl2(DMSO-S)2(H2NCH2CH 2P(O)Ph2-N,O)] (4) containing an oxidised aminophosphine ligand is also reported.