50550-52-2Relevant articles and documents
The photochemical generation of α-sulfur-substituted cyclopropylcarbinyl radicals and their utilization as a mechanistic probe for electron transfer in the peroxide-sulfide reaction
Adam, Waldemar,Heil, Markus
, p. 1730 - 1736 (2007/10/02)
The photolytically induced n-Bu3SnH reduction of α-chloro-substituted sulfides 4 and photochemical addition of BrCCl3 to thiones 7 afford α-sulfur-substituted cyclopropylcarbinyl radicals, which rearrange efficiently to afford thioen
Selective Condensation of titanium Reagent with Carbonyl Compounds
Furuta, Kyoji,Ikeda, Yoshihiko,Meguriya, Noriyuki,Ikeda, Nobuo,Yamamoto, Hisashi
, p. 2781 - 2790 (2007/10/02)
titanium reagent generated easily from allyl ethyl sulfides condensed with aldehydes to give erythro-β-hydroxy sulfides in highly regio- and stereoselective manner.In contrast, crotyl ethyl sulfide reacted with aldehydes affording δ-hydroxy vinyl sulfide exclusively.The substitution pattern of the starting sulfide can have a pronounced effect on the selectivity in this condensation reaction, erythro-β-Hydroxy sulfide obtained was transfromed stereoselectively to the trans-vinyloxirane or 1,3-alkadiene.