50598-99-7Relevant articles and documents
Regioselectivity in the rhodium catalysed 1,4-hydrosilylation of isoprene. Aspects on reaction conditions and ligands
Gustafsson, Magnus,Frejd, Torbj?rn
, p. 438 - 443 (2004)
The regioselectivity in the Rh catalysed 1,4-hydrosilylation of isoprene was investigated. Variation of solvents and temperature did not significantly affect the isomer distribution between tail-product (I) and head-product (II). The choice of ligands had
The effect of oxygen on the regioselectivity in the rhodium catalysed hydrosilylation of 1,3-dienes
Gustafsson, Magnus,Frejd, Torbjoern
, p. 102 - 107 (2007/10/03)
The regioselectivity of the hydrosilylation of substituted 1,3-dienes catalysed by several rhodium complexes in the presence and absence of oxygen was studied. In addition to the already known accelerating effect, the presence of oxygen strongly affected