50649-66-6

Basic information

• Product Name: 4-(methoxycarbonyl)phenyl 4-methoxybenzoate
• Synonyms: 4-(methoxycarbonyl)phenyl 4-methoxybenzoate
• CAS NO: 50649-66-6
• Molecular Formula: C₁₆H₁₄O₅
• Molecular Weight: 286.27936
• Mol File: 50649-66-6.mol
• Article Data: 7

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 4-(methoxycarbonyl)phenyl 4-methoxybenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(methoxycarbonyl)phenyl 4-methoxybenzoate(50649-66-6)
• EPA Substance Registry System: 4-(methoxycarbonyl)phenyl 4-methoxybenzoate(50649-66-6)

Safety Data

• Hazardous Substances Data: 50649-66-6(Hazardous Substances Data)

Upstream product

• 100-09-4 4-methoxybenzoic acid 
• 99-76-3 methyl 4-hydroxylbenzoate 
• 619-44-3 methyl 4-iodobenzoate 
• 6018-89-9 nickel(II) acetate tetrahydrate 
• 121-98-2 methyl 4-methoxybenzoate 
• 99-96-7 4-hydroxy-benzoic acid 
• 77750-05-1 4-methoxy-thiobenzoic acid S-(4-nitro-phenyl ester) 
• 21122-37-2 S-phenyl 4-methoxybenzothioate 
• 24642-86-2 2,4-dinitrophenyl 4-methoxybenzoate 

Downstream Products

• 52899-69-1 4-(4'-methoxybenzoyloxy)benzoic acid 

Relevant articles and documents

PEROVSKITES FOR PHOTOCATALYTIC ORGANIC SYNTHESIS

Nature is capable of storing solar energy in chemical bonds via photosynthesis through a series of C—C, C—O and C—N bond-forming reactions starting from CO2 and light. Direct capture of solar energy for organic synthesis is a promising approach

Semi-heterogeneous Dual Nickel/Photocatalysis using Carbon Nitrides: Esterification of Carboxylic Acids with Aryl Halides

Cross-coupling reactions mediated by dual nickel/photocatalysis are synthetically attractive but rely mainly on expensive, non-recyclable noble-metal complexes as photocatalysts. Heterogeneous semiconductors, which are commonly used for artificial photosynthesis and wastewater treatment, are a sustainable alternative. Graphitic carbon nitrides, a class of metal-free polymers that can be easily prepared from bulk chemicals, are heterogeneous semiconductors with high potential for photocatalytic organic transformations. Here, we demonstrate that graphitic carbon nitrides in combination with nickel catalysis can induce selective C?O cross-couplings of carboxylic acids with aryl halides, yielding the respective aryl esters in excellent yield and selectivity. The heterogeneous organic photocatalyst exhibits a broad substrate scope, is able to harvest green light, and can be recycled multiple times. In situ FTIR was used to track the reaction progress to study this transformation at different irradiation wavelengths and reaction scales.

New hockey stick shaped amino allylidene (?N?CH?CH?CH) based compounds: Effect of linkage group on mesomorphic properties

Two nonlinear hockey stick shaped homologous series based on three linking groups have been synthesized and characterized by elemental analyses and spectroscopic techniques. The mesomorphic properties of these compounds were observed by polarizing optical microscopy (POM) and differential scanning calorimetry (DSC). In this present investigation, we have synthesized two homologous series viz. 2-((3-phenyl allylidene) amino) phenyl 4-((4-n-alkoxy benzylidene) amino) benzoate (series-1) and 4-((2-((3-phenyl allylidene) amino) phenoxy) carbonyl) phenyl-4-n-alkoxy benzoate (series-2). Both the series are differing with respect to first linking group. In series-1, comp.C4-C18 shows nematic as well as smectic phase while in series-2, comp.C10-C16 shows smectic and nematic phase while comp.C4-C18 shows only nematic phase.