5070-24-6

Basic information

• Product Name: bicyclopentyl-2,2'-dione
• Synonyms: bicyclopentyl-2,2'-dione
• CAS NO: 5070-24-6
• Molecular Weight: 166.22
• Mol File: 5070-24-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: bicyclopentyl-2,2'-dione(CAS DataBase Reference)
• NIST Chemistry Reference: bicyclopentyl-2,2'-dione(5070-24-6)
• EPA Substance Registry System: bicyclopentyl-2,2'-dione(5070-24-6)

Safety Data

• Hazardous Substances Data: 5070-24-6(Hazardous Substances Data)

Upstream product

• 13735-81-4 1-styrenyloxytrimethylsilane 
• 19980-43-9 1-(trimethylsilyloxy)cyclopentene 
• 110-82-7 cyclohexane 
• 120-92-3 cyclopentanone 
• 66324-10-5 tert-butyldimethyl(1-phenylvinyloxy)silane 
• 17851-96-6 2-Tributylstannyl-cyclopentanon 
• 60-29-7 diethyl ether 
• 7553-56-2 iodine 
• 611-10-9 2-ethoxycarbonyl-1-cyclopentanone 

Downstream Products

• 39516-91-1 5-decenedioic acid 
• 125731-26-2 4-(4-Methoxy-phenyl)-2,3,4,5,6,7-hexahydro-1H-dicyclopenta[b,d]pyrrole 
• 125757-87-1 4-p-Tolyl-2,3,4,5,6,7-hexahydro-1H-dicyclopenta[b,d]pyrrole 
• 125731-23-9 4-(3-Trifluoromethyl-phenyl)-2,3,4,5,6,7-hexahydro-1H-dicyclopenta[b,d]pyrrole 
• 125731-24-0 4-(2-Methoxy-phenyl)-2,3,4,5,6,7-hexahydro-1H-dicyclopenta[b,d]pyrrole 
• 125731-25-1 4-(3-Methoxy-phenyl)-2,3,4,5,6,7-hexahydro-1H-dicyclopenta[b,d]pyrrole 
• 125731-22-8 4-(4-Fluoro-phenyl)-2,3,4,5,6,7-hexahydro-1H-dicyclopenta[b,d]pyrrole 
• 125731-28-4 C₂₆H₂₈N₂ 
• 125731-27-3 4-(1,2,3,5,6,7-Hexahydro-dicyclopenta[b,d]pyrrol-4-yl)-phenylamine 
• 125731-21-7 4-Phenyl-2,3,4,5,6,7-hexahydro-1H-dicyclopenta[b,d]pyrrole 

Relevant articles and documents

Oxidative Generation of α-Radicals of Carbonyl Compounds from the α-Stannyl Derivatives and Their Reactions with Electron-Rich Olefins

The oxidation of α-tributylstannyl alkanoates with tetrabutylammonium hexanitratocerate(IV) generates α-radicals of the alkanoates by eliminating the stannylium ion.The thus-formed radicals react with various electron-rich olefinic compounds, such as silyl enol ethers, giving addition products in good yield.This method formally achieves selective cross coupling between alkanoates and ketones.

DEHYDRODIMERIZATION OF KETONES, CARBOXYLIC ACIDS, AMIDES, ESTERS, ALCOHOLS, AND AMINES, VIA MERCURY-PHOTOSENSITIZATION

Selective dehydrodimerization of the title compounds can be carried out on a preparative scale at 1 atm. and at 25-110 deg C in a simple apparatus by Hg-photosensitized reaction under H2.