51338-27-3 Usage
Chemical Properties
A white crystalline solid. Odorless. Can also
be commercially available as a clear to dark brown liquid
with a typical solvent odor
Uses
Herbicide.
General Description
Colorless crystals. Decomposed by either strong acid or base. Used as a selective herbicide.
Air & Water Reactions
Slightly soluble in water (3 mg/l).
Reactivity Profile
A bridged diphenyl.
Agricultural Uses
Herbicide: Some uses are classified as U.S. Restricted
Use Pesticide (RUP). Diclofop-methyl is a selective
post-emergence herbicide used to control wild oats and
annual grassy weeds in grain and vegetable crops: alfalfa,
carrots, celery, box, field and french beans, barley,
wheat, brassicas, parsnips, peas, potatoes, rapeseed
(canola), soy beans, oilseed rape, onions, sugar beets and
lettuce.
Trade name
DICHLORDIPHENPROP?; HOELON?;
HOELON? 3EC; HOE-GRASS?; HOEGRASS?; HOE?
23408; ILOXAN?; ILLOXAN?; ONE SHOT?[C]
Potential Exposure
Diclofop-methyl is a chlorophenoxy;
aryloxyphenoxypropionate acid selective postemergenceherbicide used to control wild oats and annual grassy weeds
in grain and vegetable crops: alfalfa, carrots, celery, box,
field and French beans, barley, wheat, brassicas, parsnips,
peas, potatoes, rapeseed (canola), soy beans, oilseed rape,
onions, sugar beets and lettuce. Some uses are classified
RUP
Environmental Fate
Biological. From the first-order biotic and abiotic rate constants of diclofop-methyl in estuarine water and sediment/water systems, the estimated biodegradation half-lives were 0.24–12.4 and 0.11–2.2 days, respectively (Walker et al., 1988).
Metabolic pathway
Two resistant biotypes of black-grass (Peldon A1 and
Lincs. E1 of Alopecurus myosuroides) exhibit
moderately enhanced metabolism of 14C-diclofop
methyl. Diclofop methyl is hydrolyzed to the
corresponding propionic acid which undergoes further
degradation to give polar metabolites. The amounts of
the metabolites depend on the metabolism activity of
the individual biotypes. In wheat, three isomeric
hydroxylated metabolites are identified in a major
metabolic pathway after acid hydrolysis of the
glucoside conjugates.
Shipping
UN3345 Phenoxyacetic acid derivative pesticide,
solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous
materials. UN3348 Phenoxyacetic acid derivative pesticide,
liquid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous
material. UN3077 Environmentally hazardous substances,
solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous
hazardous material, Technical Name Required. Note:
Commercial product may also be a liquid in a flammable
carrier.
Incompatibilities
Incompatible with oxidizers, chlorates
nitrates, peroxides, sulfuric acid, caustics, ammonia,
aliphatic amines, alkanolamines, isocyanates, alkylene
oxides, and epichlorohydrin.
Waste Disposal
In accordance with
40CFR165, follow recommendations for the disposal of
pesticides and pesticide containers. Containers must be disposed of properly by following package label directions or
by contacting your local or federal environmental control
agency, or by contacting your regional EPA office
Check Digit Verification of cas no
The CAS Registry Mumber 51338-27-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,1,3,3 and 8 respectively; the second part has 2 digits, 2 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 51338-27:
(7*5)+(6*1)+(5*3)+(4*3)+(3*8)+(2*2)+(1*7)=103
103 % 10 = 3
So 51338-27-3 is a valid CAS Registry Number.
InChI:InChI=1/C16H14Cl2O4/c1-10(16(19)20)9-21-12-3-5-13(6-4-12)22-15-7-2-11(17)8-14(15)18/h2-8,10H,9H2,1H3,(H,19,20)/p-1
51338-27-3Relevant articles and documents
NOXIOUS ARTHROPOD CONTROL AGENT CONTAINING AMIDE COMPOUND
-
, (2017/08/26)
An object of the present invention is to provide a compound having the controlling activity on a noxious arthropod, and a noxious arthropod controlling agent containing an amide compound of formula (I): wherein X represents a nitrogen atom or a CH group, p represents 0 or 1, A represents a tetrahydrofuranyl group or the like, R1, R2, R3, R4, R5, R6 and R7 represent a hydrogen atom or the like, n represents 1 or 2, Y represents an oxygen atom or the like, m represents any integer of 0 to 7, and Q represents a C1-8 chain hydrocarbon group optionally having a phenyl group or the like, has the excellent noxious arthropod controlling effect.
Herbicidal esters of D-1-(phenoxy-4-phenoxy)propionic acid
-
, (2008/06/13)
Optically active enantiomers of the formula I STR1 where R is a group of the formulae STR2 R1 and R2, among others, are halogen or CF3 and Z is a carboxyl, carboxylate, carboxylic acid ester, thioester, carbonamide, carboxylic acid anilide, carbohydrazide or thioamide group, are interesting herbicides the effect of which is considerably superior to that of the optically inactive racemates.
5,6-Dihydro-1,2,4,6-thiatriazin-5-one-1,1-dioxides
-
, (2008/06/13)
5,6-Dihydro-1,2,4,6-thiatriazin-5-one-1,1-dioxides of the formula STR1 where R1 is hydrogen, a metal atom or an unsubstituted or substituted ammonium radical, R2 is a saturated or unsaturated straight-chain aliphatic radical of up to 10 carbon atoms, a cycloaliphatic radical or 3 to 7 carbon atoms, a branched saturated or unsaturated aliphatic radical of 3 to 10 carbon atoms, a halogen-, alkoxy- or alkylmercapto-substituted aliphatic radical of 2 to 10 carbon atoms tetrahydrofuryl substituted methyl, a cycloalkoxy-substituted aliphatic radical of 4 to 10 carbon atoms, unsubstituted or halogen-substituted benzyl or phenyl, halophenyl, or alkylphenyl of a total of up to 10 carbon atoms, R3 is hydrogen, a straight-chain aliphatic radical of up to 10 carbon atoms, a cycloaliphatic radical of 3 to 7 carbon atoms, a branched aliphatic radical of 3 to 10 carbon atoms, haloalkyl, or alkoxyalkyl of 2 to 10 carbon atoms and X is oxygen and may also be sulfur if R2 is unsubstituted or halogen-substituted benzyl, processes for their preparation, and herbicides containing the above compounds.
