51533-22-3

Basic information

• Product Name: Benzene, [(2-methoxycyclohexyl)seleno]-, trans-
• CAS NO: 51533-22-3
• Molecular Formula: C13H18OSe
• Molecular Weight: 269.245
• Mol File: 51533-22-3.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Benzene, [(2-methoxycyclohexyl)seleno]-, trans-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(2-methoxycyclohexyl)seleno]-, trans-(51533-22-3)
• EPA Substance Registry System: Benzene, [(2-methoxycyclohexyl)seleno]-, trans-(51533-22-3)

Safety Data

• Hazardous Substances Data: 51533-22-3(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 1666-13-3 diphenyl diselenide 
• 110-83-8 cyclohexene 
• 133708-80-2 benzeneselenenyl m-nitrobenzenesulfonate 

Downstream Products

• 29887-56-7 trans-1,2-dimethoxycyclopentane 
• 19752-95-5 1,2-dimethoxycyclohexane 
• 872-53-7 cyclopentanealdehyde 
• 30363-80-5 cis-1.2-dimethoxy-cyclohexane 
• 29887-60-3 trans-1,2-dimethoxycyclohexane 

Relevant articles and documents

Visible-light-promoted selenofunctionalization of alkenes

A visible-light-promoted method for the selenofunctionalization (and tellurofunctionalization) of alkenes has been developed. This method obviates the prepreparation of moisture-sensitive chalcogen electrophiles. The experimental setup is simple, and supe

Oxidation of diphenyl diselenide with 2,3-dichloro-5,6-dicyanobenzoquinone (DDQ). A new method for the electrophilic phenylselenenylation of alkenes under mild conditions

The oxidation of diphenyl diselenide with 2,3-dichloro-5,6-dicyanobenzoquinone (DDQ) represents a convenient mild method to produce a strongly electrophilic phenylselenium reagent. Clean phenylseleno methoxylations and hydroxylations of alkenes containing different types of functional groups can be effected by working in methanol or in acetonitrile and water, respectively. This new electrophilic reagent can also be employed to promote efficient cyclization reactions of alkenols to tetrahydrofurans or of alkenoic acids to lactones.

Oxidative Cleavage of Diselenide by m-Nitrobenzenesulfonyl Peroxide. Novel Method for the Electrophilic Benzeneselenenylations of Olefins and Aromatic Rings

Diphenyl diselenide was found to be readily converted into benzeneselenenyl-m-nitrobenzenesulfonate (PhSeOSO2C6H4NO2-m) by treating with m-nitrobenzenesulfonyl peroxide.When the selenenyl sulfonate thus formed was allowed to react in situ with olefins, such as cyclohexene, 1-octene, or styrene, in the presence of various nucleophiles, the adducts of benzeneselenenyl group and a nucleophile were obtained.As the nucleophiles water, methanol, acetic acid, phenol, and anisole could be employed; oxyselenenylated : R=H, Me, Ac, and Ph) and arylselenenylated : R=H and Me) adducts were afforded.Phenol gave oxyselenenylated products in cyclohexene or 1-octene and arylselenenylated products in styrene.Efficient intramolecular cyclizations of unsaturated alcohols and carboxylic acids were similarly performed by the selenenyl sulfonate to afford corresponding benzeneselenenylated cyclic ethers and lactones.The selenenyl sulfonate was also found to be a highly reactive benzeneselenenylating reagent for aromatic rings, such as anisole, phenol, acetanilide, toluene, and benzene.