51755-60-3

Basic information

• Product Name: 1,1,1,3-TETRACHLORODECANE
• Synonyms: 1,1,1,3-TETRACHLORODECANE
• CAS NO: 51755-60-3
• Molecular Formula: C10H18Cl4
• Molecular Weight: 280.06
• Mol File: 51755-60-3.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 298.0±8.0 °C(Predicted)
• Appearance: /
• Density: 1.169±0.06 g/cm3(Predicted)
• CAS DataBase Reference: 1,1,1,3-TETRACHLORODECANE(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1,1,3-TETRACHLORODECANE(51755-60-3)
• EPA Substance Registry System: 1,1,1,3-TETRACHLORODECANE(51755-60-3)

Safety Data

• Hazardous Substances Data: 51755-60-3(Hazardous Substances Data)

Usage

Uses

1,1,1,3-Tetrachlorodecane is used in the synthesis of bis(2-pyridylmethyl)amine copper complexes, which exhibits catalytic activity.Also, it is derived from Carbon Tetrachloride (C176905), which is used in biological studies to evaluate the genotoxicity and toxicity in primary hepatocyte culture of humans and lab animals.Persistent environmental pollutant.

Upstream product

• 2547-61-7 Trichloromethanesulfonyl chloride 
• 124-11-8 non-1-ene 
• 872-05-9 1-Decene 
• 56-23-5 tetrachloromethane 

Relevant articles and documents

Synthesis, characterization, X-ray crystallography analysis, and catalytic activity of bis(2-pyridylmethyl)amine copper complexes containing coupled pendent olefinic arms in atom transfer radical addition (ATRA) reactions

The synthesis, characterization, and catalytic activity of bis(2-pyridylmethyl)amine (BPMA) copper complexes incorporating olefinic pendent arms are reported. Four copper(I) and four copper(II) complexes were synthesized employing four different counterions [chloride (Cl-), perchlorate (ClO4-), trifluoromethanesulfonate (CF3SO3-), and tetraphenylborate (BPh4-)]. The counterions used ranged from coordinating (Cl-) to non-coordinating (BPh4-), producing different coordination modes in respective complexes. Solid state results obtained for the copper(I) complex incorporating the non-coordinating (BPh4-) counterion displayed an associative bond between the metal center and the C=C group in the olefinic arm of a neighboring complex. This interaction led to augmentation of the C=C bond due to back-bonding from the metal center. Five solid state structures were obtained for the copper(II) complexes with two also displaying intermolecular associative bonding between olefinic pendent arms and the metal center. X-ray crystallography studies showed that the olefinic arm motifs incorporated were hemilabile. Solution studies indicated that the copper complexes had some inherent reducing power and could be potential candidates for use as catalysts in atom transfer radical processes. However, only moderate conversions and yields were obtained in atom transfer radical addition (ATRA) reaction studies performed utilizing the copper complexes due to the presence of a competing reaction.

ADDITION OF SULFONYL CHLORIDES TO OLEFINS IN THE PRESENCE OF CATALYTIC AMOUNTS OF DICHLOROTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II)

Reactions of sulfonyl chlorides with olefins catalysed by dichlorotris(triphenylphosphine)ruthenium(II) have been studied.Methanesulfonyl and arenesulfonyl chlorides added to 1-alkenes to give 1 : 1 adducts in high yields.Telomer formation is not observed, therefore the present reaction provides a general and convenient method for synthesis of β-chlorosulfones.A radical-chain mechanism is proposed for the reaction.