52323-94-1

Basic information

• Product Name: Stannane, trimethyl(4-nitrophenyl)-
• CAS NO: 52323-94-1
• Molecular Formula: C9H13NO2Sn
• Molecular Weight: 285.918
• Mol File: 52323-94-1.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Stannane, trimethyl(4-nitrophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Stannane, trimethyl(4-nitrophenyl)-(52323-94-1)
• EPA Substance Registry System: Stannane, trimethyl(4-nitrophenyl)-(52323-94-1)

Safety Data

• Hazardous Substances Data: 52323-94-1(Hazardous Substances Data)

Upstream product

• 636-98-6 p-nitrobenzene iodide 
• 661-69-8 hexamethyldistannane 
• 586-78-7 para-nitrophenyl bromide 
• 56075-39-9 1-(methylsulfonyl)-2-(4-nitrophenyl)diazene 
• 100-01-6 4-nitro-aniline 
• 106-37-6 1.4-dibromobenzene 
• 1012-73-3 1,4-bis(trimethylstannyl)benzene 

Downstream Products

• 1144-74-7 4-nitrobenzophenone 
• 115755-53-8 (1-benzoylpiperidin-4-yl)(4-nitrophenyl)methanone 
• 100229-07-0 (1,2,5,6-η4-cyclooctadiene)(2,4-dinitrophenyl)(4-nitrophenyl)platinum(II) 
• 92-93-3 1-phenyl-4-nitrobenzene 
• 1528-74-1 4,4'-dinitrobiphenyl 
• 80245-34-7 4-nitro-4’-(trifluoromethyl)biphenyl 
• 2143-90-0 4-methoxy-4'-nitrobiphenyl 
• 107624-96-4 3-methoxy-4'-nitro-1,1'-biphenyl 
• 67408-05-3 Pt(C₆H₄NO₂-p)2(1,2-bis(diphenylphosphino)ethane) 
• 910327-35-4 dimethyl-bis(4-nitrophenyl)stannane 
• 636-98-6 p-nitrobenzene iodide 
• 126086-79-1 1-dimethyl-chlorostannyl-4-nitrobenzene 
• 139418-53-4 nitroaltanserin 
• 98-95-3 nitrobenzene 

Relevant articles and documents

Visible-Light-Driven Synthesis of Arylstannanes from Arylazo Sulfones

The visible-light-driven preparation of (hetero)aryl stannanes was carried out under both photocatalyst- and metal-free conditions via irradiation of arylazo sulfones in the presence of hexaalkyldistannanes. The reaction shows a high efficiency and a wide substrates scope. The resulting crude organotin derivatives can be directly employed in a Stille protocol.

Synthesis of aryl trimethylstannanes from aryl amines: A sandmeyer-type stannylation reaction

Sandmeyer-type stannylation: Stille coupling is one of the most powerful coupling reactions for C-C bond formation, whereas there are only limited methods to access aryl stannane compounds. A mild stannylation process based on a Sandmeyer-type transformation using aromatic amines as the starting materials is described. DCE: 1,2-dichloroethane. Copyright

Rapid synthesis of F-18 and H-2 dual-labeled altanserin. A metabolically resistant PET ligand for 5-HT(2A) receptors

F-18 and H-2 dual-labeled altanserin (3, [18F]d-ALT), a novel PET tracer for 5-HT(2A) receptors with metabolically resistant properties, was synthesized by [18F]fluoride displacement of the corresponding deuterated nitro precursor in 32% yield (EOB) in 108 min with radiochemical purity 95% and specific activity > 1000 mCi/μmol (EOS). The key intermediate ethyl N-(2-chloroethyl-2,2-d2)carbamate (7) was obtained by LiAID4 reduction of a glycine ester (93%), chlorination and carbamoylation (79%). 4-(4-Nitrobenzoyl)piperidine (13) was synthesized (60%) by improving the published coupling reaction of p-nitrophenyltrimethylstannane (10), obtained from p-iodonitrobenzene and (CH3)6Sn2 (94%), with 1-benzoylisonipecotic acid chloride (11) followed by acid hydrolysis. 13 was alkylated with 7 (82%), hydrolyzed and condensed with methyl o-isothiocyanatobenzoyate to provide with the precursor deuteronitroaltanserin (4, 75%).