52485-06-0

Basic information

• Product Name: 3,4,6-tri-O-acetyl-D-glucal
• Synonyms: 3,4,6-tri-O-acetyl-D-glucal
• CAS NO: 52485-06-0
• Molecular Weight: 272.255
• Mol File: 52485-06-0.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 3,4,6-tri-O-acetyl-D-glucal(CAS DataBase Reference)
• NIST Chemistry Reference: 3,4,6-tri-O-acetyl-D-glucal(52485-06-0)
• EPA Substance Registry System: 3,4,6-tri-O-acetyl-D-glucal(52485-06-0)

Safety Data

• Hazardous Substances Data: 52485-06-0(Hazardous Substances Data)

Upstream product

• 75-65-0 tert-butyl alcohol 
• 572-09-8 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide 
• 108-24-7 acetic anhydride 
• 66966-07-2 α/β‐L‐glucopyranosyl‐1,2,3,4,5‐pentaacetate 
• 138514-70-2 peracetyl-L-glucosyl bromide 
• 67337-79-5 2,3,4,6-tetra-O-acetyl-α-L-glucopyranosyl bromide 

Downstream Products

• 65914-22-9 1,4,6-Tri-O-acetyl-α,β-D-erythro-hex-2-enopyranose (Pseudo-C-glucal triacetate) 
• 2873-29-2 D-glucal triacetate 
• 71442-92-7 1-<(2-hydroxy)ethyl>-1-vinylcyclohexane 
• 4441-58-1 4-Cyclohexylidenebutan-1-ol 
• 78465-52-8 (2R,3R,6S)-2-(acetoxymethyl)-6-phenyl-3,6-dihydro-2H-pyran-3,4-diyl diacetate 
• 78465-54-0 (3,4,6-tri-O-acetyl-2-deoxy-α-D-threo-hex-2-enopyranosyl)benzene 
• 81389-84-6 benzyl 4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-enpyranoside 
• 81389-85-7 benzyl 4,6-di-O-acetyl-2,3-dideoxy-β-D-erythrohex-2-enopyranoside 
• 61243-05-8 (S)-1-(α-furyl)-1,2-ethanediol 
• 1356155-30-0 3,4,6-tri-O-acetyl-1,5-anhydro-2-thio-2-S-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-D-altritol 
• 5207-08-9 bis(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)disulfide 
• 6806-56-0 O²,O³,O⁴,O⁶,S-Pentaacetyl-1-thio-β-D-glucopyranose 
• 13265-84-4 1,2-didehydrodideoxyallose 
• 1393354-13-6 C₂₇H₂₉FO₅ 

Relevant articles and documents

Bisindolylmaleimide derivative, and preparation method and use thereof

The invention provides a bisindolylmaleimide derivative, and a preparation method and a use thereof. The bisindolylmaleimide derivative has a good tumor treatment effect, especially has a good treatment effect on some drug-resistant tumors, and can realize accurate treatment of the drug-resistant tumors.

NaBH3CN: A janus substitute for tin-free radical-based reactions

Beside showing that thermal radical reactions (reduction, Giese reaction) are efficient if bromo-/iodosugars are treated with NaBH3CN and 2,2″-azobisisobutyronitrile, we explored new initiation conditions on the basis of CuI salts (≤0.5 equiv.) supposed to produce radicals from organobromides through a set. This was confirmed, as at about 50 C under an inert atmosphere acetobromoglucose was reduced to the rearranged 2-deoxyglucose and as N-allyl α-bromoamides reacted, depending on the conditions, either by reductive cyclization or atom-transfer radical cyclization. A related cyclization occurred upon using Cu(OAc)2. This and other assays showed the reduction by NaBH3CN of CuII salts, either added or formed in situ. Having both ionic and radical reactivity, NaBH 3CN appears as a Janus reagent that may be useful for tin-free radical chemistry under mild and very simple conditions. Copyright

Syntheses of l-glucosamine donors for 1,2-trans-glycosylation reactions

Two new l-glucosamine donors, that is pent-4-enyl 3,4,6-tri-O-acetyl-2-allyloxycarbonylamino-2-deoxy-β-l-glucopyranos ide 16 and ethyl 3,4,6-tri-O-acetyl-2-allyloxycarbonylamino-2-deoxy-1-thio-β-l-gluco pyranoside 21 were prepared in 12 steps from l-arabinose. The reaction pathway uses 3,4,6-tri-O-acetyl-l-glucal 5, and then 3,4,6-tri-O-acetyl-2-deoxy-2-iodo-α-l-mannopyranosyl azide 8 as intermediates. The latter, together with donors 16 and 21, were used for preparing l-glucosamine neoglycolipids.