52562-19-3

Basic information

• Product Name: 2-ISOPROPENYLANILINE
• Synonyms: 2-(1-methylethenyl)-benzenamin;o-Isopropenylaniline;2-ISOPROPENYLANILINE;2-ISOPROPENYLANILINE, 98+%;2-Isopropenylaniline, GC 98+%;2-(1-Methylethenyl)benzenamine;2-(1-Methylvinyl)aniline;2-(1-Propene-2-yl)benzeneamine
• CAS NO: 52562-19-3
• Molecular Formula: C₉H₁₁N
• Molecular Weight: 133.19
• EINECS: 258-008-7
• Product Categories: Monomers;Polymer Science;Styrene and Functionalized Styrene Monomers
• Mol File: 52562-19-3.mol
• Article Data: 51

Chemical Properties

• Boiling Point: 95 °C13 mm Hg(lit.)
• Flash Point: 173 °F
• Appearance: /
• Density: 0.978 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.173mmHg at 25°C
• Refractive Index: n20/D 1.57(lit.)
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• PKA: 3?+-.0.10(Predicted)
• BRN: 3081217
• CAS DataBase Reference: 2-ISOPROPENYLANILINE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-ISOPROPENYLANILINE(52562-19-3)
• EPA Substance Registry System: 2-ISOPROPENYLANILINE(52562-19-3)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36
• WGK Germany: 3
• Hazardous Substances Data: 52562-19-3(Hazardous Substances Data)

Usage

Chemical Properties

CLEAR SLIGHTLY YELLOW LIQUID

InChI:InChI=1/C9H11N/c1-7(2)8-5-3-4-6-9(8)10/h3-6H,1,10H2,2H3

Upstream product

• 551-93-9 2-aminoacetophenone 
• 74-88-4 methyl iodide 
• 120780-18-9 3-Bromo-4-methyl-2-p-tolyl-2λ⁴-benzo[c][1,2]thiazine 2-oxide 
• 75-16-1 methylmagnesium bromide 
• 577-59-3 2-acetylnitrobenzene 
• 102968-92-3 2-isopropylthio-N-allylaniline 
• 74-83-9 methyl bromide 
• 552-89-6 2-nitro-benzaldehyde 
• 615-36-1 2-bromoaniline 
• 1885-29-6 anthranilic acid nitrile 
• 2065-66-9 methyl-triphenylphosphonium iodide 
• 490035-95-5 N-benzyl-2-(prop-1-en-2-yl)benzen-amine 
• 62-53-3 aniline 
• 74-99-7 prop-1-yne 

Downstream Products

• 643-28-7 2-isopropylaniline 
• 133901-65-2 2,2-Dichloro-N-acetamide 
• 119449-51-3 N-(2-Isopropenyl-phenyl)-propionamide 
• 106012-41-3 N-[2-(1-methylethenyl)phenyl]benzamide 
• 97691-25-3 2-tert-butyl-4-methylquinoline 
• 115307-46-5 N-(2,2-dimethylethyl)-2-(2-propenyl)benzeneamine 
• 88884-37-1 N-benzoyl-N'-2-isopropenylphenylthiourea 
• 858621-23-5 N-[2-(1-methylethenyl)phenyl]trifluoroacetamide 
• 19343-78-3 4-methyl-1,2,3,4-tetrahydroquinoline 
• 7117-17-1 N-methyl-2-(1-methylethenyl)benzenamine 
• 1346130-53-7 C₁₈H₁₉N 
• 1346130-50-4 (S)-N-(1-phenylallyl)-2-(prop-1-en-2-yl)aniline 
• 1346130-51-5 C₁₈H₁₉N 
• 1346130-62-8 (S)-N-(1-(3-chlorophenyl)allyl)-2-(prop-1-en-2-yl)aniline 

Relevant articles and documents

PHOTOCHEMICAL SYNTHESIS OF MARMYCIN ANALOGUES THROUGH A NEW PHOTOCHEMICAL REACTION INVOLVING CARBONYL COMPOUNDS

Photochemical reactivity of carbonyl compounds leading to the synthesis of the Marmycin core is described. The photochemical reactivity involves an excited state reaction that provides convenient access to bicyclic compounds. The disclosed reactivity is a

Synthesis of 1-Amino-2,2,2-trifluoroalkylphosphonates from Alkene-Tethered Trifluoroacetimidoyl Chlorides

The reaction of alkene-tethered trifluoroacetimidoyl chlorides with trialkyl phosphites furnishes 1-amino-2,2,2-trifluoroalkylphosphonates. The products were generated in moderate to good yields, and the scalability of this process was showcased. Partial hydrolysis of the phosphonate moiety was achieved. The cyclization is proposed to occur via formation of an imidoyl phosphonate intermediate that becomes susceptible to nucleophilic attack at nitrogen through the strong electron-withdrawing groups at the imidoyl carbon.

Uncovering New Excited State Photochemical Reactivity by Altering the Course of the de Mayo Reaction

An unprecedented and previously unknown photochemical reactivity of 1,3-dicarbonyl compounds is observed with amino-alkenes leading to dihydropyrans. This novel photochemical reactivity changes the established paradigm related to the De Mayo reaction between 1,3-dicarbonyl compounds and alkenes. This new reaction allows convenient access to the Marmycin core in a single step from commercially available reactants. The origin and scope of this new photoreaction is detailed with preliminary photophysical and mechanistic investigations.