5309-67-1Relevant articles and documents
HYDROCHLORINATION OF VINYL AND ALLYL ACRYLATES AND TRANS-CROTONATES
Komarova, L. I.,Zhuravleva, E. I.
, p. 455 - 457 (2007/10/02)
Different orders of addition were established for the addition of hydrogen chloride to vinyl and allyl acrylates and trans-crotonates.The hydrochlorination of vinyl and allyl acrylates takes place regioselectively at the double bond of the acrylic system.The hydrochlorination of vinyl and allyl trans-crotonates takes place at the double bond of the alkenoxy group.Vinyl β-chloropropionate and β-chlorobutyrate were also obtained by transvinylation of the acids with vinyl acetate.The ability of the obtained chloroesters to undergo certain chemical transformations was demonstrated.