53778-56-6Relevant articles and documents
Palladium-Catalyzed Intramolecular Cyanosilylation of Alkynes Leading to Stereoselective Synthesis of α,β-Unsaturated Nitriles
Suginome, Michinori,Kinugasa, Hiroshi,Ito, Yoshihiko
, p. 8635 - 8638 (2007/10/02)
Intramolecular cyanosilylation was achieved by the reaction of chlorodiphenylsilyl ether of homopropargylic alcohols with trimethylsilylcyanide in the presence of palladium catalyst. The reaction proceeded regio- and stereoselectively to give (Z)-3-(1-cya