53812-68-3

Basic information

• Product Name: 1,1'-BIPHENYL, 4'-METHYL-3-NITRO-
• Synonyms: 1,1'-BIPHENYL, 4'-METHYL-3-NITRO-;4'-Methyl-3-nitro-1,1'-biphenyl;1-Methyl-4-(3-nitrophenyl)benzene
• CAS NO: 53812-68-3
• Molecular Formula: C₁₃H₁₁NO₂
• Molecular Weight: 213.23194
• Mol File: 53812-68-3.mol
• Article Data: 6

Chemical Properties

• Melting Point: 78 °C(Solv: ethanol (64-17-5))
• Boiling Point: 349.9±21.0 °C(Predicted)
• Appearance: /
• Density: 1.166±0.06 g/cm3(Predicted)
• CAS DataBase Reference: 1,1'-BIPHENYL, 4'-METHYL-3-NITRO-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1'-BIPHENYL, 4'-METHYL-3-NITRO-(53812-68-3)
• EPA Substance Registry System: 1,1'-BIPHENYL, 4'-METHYL-3-NITRO-(53812-68-3)

Safety Data

• Hazardous Substances Data: 53812-68-3(Hazardous Substances Data)

Usage

General Description

4'-Methyl-3-nitro-1,1'-biphenyl is a chemical compound with the molecular formula C13H11NO2. It is a derivative of biphenyl, which is a common organic compound used in the production of dyes, pesticides, and other industrial applications. The addition of a methyl group and a nitro group to the biphenyl structure changes its physical and chemical properties, making it potentially useful in various applications. 1,1'-BIPHENYL, 4'-METHYL-3-NITRO- has not been extensively studied or utilized, but it has the potential for further research and development in the field of organic chemistry and industrial chemistry.

Upstream product

• 585-79-5 m-nitrobromobenzene 
• 5142-75-6 tri(p-tolyl)bismuth 
• 106-43-4 para-chlorotoluene 
• 18312-48-6 potassium m-nitrobenzoate 
• 121-92-6 3-nitrobenzoic acid 
• 106-38-7 para-bromotoluene 
• 98-95-3 nitrobenzene 
• 624-31-7 4-tolyl iodide 
• 106-49-0 p-toluidine 
• 51274-57-8 1-(4-Methylphenyl)-3,3-(1,5-pentanediyl)triazene 

Downstream Products

• 1417334-79-2 C₂₂H₁₅N₃O₅S 
• 1417334-72-5 C₂₃H₁₇N₃O₅S 
• 5737-85-9 3'-nitro-biphenyl-4-carboxylic acid 

Relevant articles and documents

Ligand-Promoted Direct C-H Arylation of Simple Arenes: Evidence for a Cooperative Bimetallic Mechanism

A highly efficient catalyst for the direct C-H arylation of simple arenes was developed on the basis of a palladium-diimine complex. The developed catalyst exhibited the highest turnover number reported to date for the direct arylation of benzene due to increased stability provided by the diimine ligand. The reaction was also performed using only 2-3 equiv of simple arenes. Mechanistic studies in combination with kinetic measurements, isotope effect experiments, synthesis of possible intermediates, and stoichiometric reactions suggested that this reaction follows a cooperative bimetallic mechanism.

A new palladium catalyzed protocol for atom-efficient cross-coupling reactions of?triarylbismuths with aryl halides and triflates

A new palladium catalyzed protocol for an atom-efficient cross-coupling reaction of triarylbismuths with aryl halides and triflates has been described. The palladium catalytic system with Cs2CO3 base was found to be very efficient in DMA solvent to furnish excellent yields of cross-coupled functionalized biaryls in short reaction times.

Synthesis of Biaryls from Aryltriazenes

Aryltriazenes react with aromatic solvents in the presence of trifluoroacetic acid to produce biaryls.The mechanism of the reaction involves the formation of arenediazonium trifluoroacetates which lose nitrogen to give mainly aryl radicals.