54191-22-9

Basic information

• Product Name: Benzene, 1-(ethoxymethyl)-4-methyl-
• CAS NO: 54191-22-9
• Molecular Formula: C10H14O
• Molecular Weight: 150.221
• Mol File: 54191-22-9.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(ethoxymethyl)-4-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(ethoxymethyl)-4-methyl-(54191-22-9)
• EPA Substance Registry System: Benzene, 1-(ethoxymethyl)-4-methyl-(54191-22-9)

Safety Data

• Hazardous Substances Data: 54191-22-9(Hazardous Substances Data)

Upstream product

• 104-82-5 4-Methylbenzyl chloride 
• 104-87-0 4-methyl-benzaldehyde 
• 79411-60-2 l'α-chloro α-ethoxymethyltributyletain 
• 93362-60-8 (Z)-1,4-Dimethyl-1,3-hexadien-5-in-1-yl-triflat 
• 4294-57-9 para-methylphenylmagnesium bromide 
• 3188-13-4 ethyl chloromethyl ether 
• 617-86-7 triethylsilane 
• 94-08-6 4-methylbenzoic acid ethyl ester 
• 64-17-5 ethanol 
• 98-80-6 phenylboronic acid 
• 2031-62-1 diethoxymethylane 
• 108-88-3 toluene 
• 75444-70-1 methyl 7,7-dichlorobicyclo<4.1.0>hept-3-ene-3-carboxylate 
• 75366-08-4 7,7-dichloro-3-hydroxymethylbicyclo<4.1.0>hept-3-ene 

Downstream Products

• 99-94-5 p-Toluic acid 
• 104-87-0 4-methyl-benzaldehyde 

Relevant articles and documents

A Versatile Iridium(III) Metallacycle Catalyst for the Effective Hydrosilylation of Carbonyl and Carboxylic Acid Derivatives

A versatile iridium(III) metallacycle catalysed rapidly and selectively the reduction of a large array of challenging esters and carboxylic acids as well as various ketones and aldehydes. The reactions proceeded in high yields at room temperature by hydrosilylation followed by desilylation. Although the reactions of various aldehydes and ketones resulted exclusively in alcohols, the hydrosilylation of esters led to alcohols or ethers, depending on the type of substrate. Regarding the carboxylic acids, again the nature of the reagent controlled the outcome of the hydrosilylation reaction, either alcohols or aldehydes being formed.

Reductive etherification of aldehydes photocatalyzed by dicarbonyl pentamethylcyclopentadienyl iron complexes

The reductive etherification of aldehydes can be performed by the reaction with dialkylmethylsilanes in the presence of new iron(II) piano-stool catalysts of general formula Cp*Fe(CO)2Ar (Cp * = η5-C5Me5; Ar = Ph, 4-C6H4OCH3, 4-C6H4CH 3, Fc). This transformation is promoted by UV light and affords a simple route for the preparation of unsymmetrical alkyl ethers.

Highly efficient indium-catalyzed chemoselective allylation-etherification and reductive etherification of aromatic aldehydes with functional silanes

Indium(III) chloride is an effective Lewis acid catalyst for one-pot allylation-etherification and reductive etherification of aromatic aldehydes with functional silanes, allyltriethoxysilane, and triethoxysilane, at room temperature to afford corresponding ethers in excellent yields. Additionally, the InCl3-catalyzed reactions in the presence of TMSCl offer significant advantages in its ease of working-up for the preparation of unsymmetrical ethers under mild conditions.