54986-63-9

Basic information

• Product Name: 5,8-DIMETHYLBENZO[C]PHENANTHRENE
• Synonyms: 5,8-DIMETHYLBENZO[C]PHENANTHRENE;AR-G51 5,8-DIMETHYLBENZO(C)PHENANTHRENE
• CAS NO: 54986-63-9
• Molecular Formula: C20H16
• Molecular Weight: 256.34104
• Mol File: 54986-63-9.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 334.58°C (rough estimate)
• Flash Point: 226.6°C
• Appearance: /
• Density: 1.0840 (estimate)
• Vapor Pressure: 2.75E-08mmHg at 25°C
• Refractive Index: 1.7290 (estimate)
• CAS DataBase Reference: 5,8-DIMETHYLBENZO[C]PHENANTHRENE(CAS DataBase Reference)
• NIST Chemistry Reference: 5,8-DIMETHYLBENZO[C]PHENANTHRENE(54986-63-9)
• EPA Substance Registry System: 5,8-DIMETHYLBENZO[C]PHENANTHRENE(54986-63-9)

Safety Data

• Hazardous Substances Data: 54986-63-9(Hazardous Substances Data)

Usage

InChI:InChI=1/C20H16/c1-13-11-15-12-14(2)17-8-4-6-10-19(17)20(15)18-9-5-3-7-16(13)18/h3-12H,1-2H3

Upstream product

• 1047647-76-6 5,6,7,8-tetrahydro-5,8-dimethylbenzo[c]phenanthrene 
• 875224-34-3 4-Methyl-2-(2-phenyl-propyl)-1,2,3,4-tetrahydro-[1]naphthol 
• 872797-44-9 4-methyl-2-(2-phenyl-propyl)-3,4-dihydro-2H-naphthalen-1-one 
• 858457-22-4 2-allyl-4-methyl-1-oxo-1,2,3,4-tetrahydro-[2]naphthaldehyde 
• 872797-29-0 2-allyl-4-methyl-3,4-dihydro-2H-naphthalen-1-one 
• 93878-28-5 β-Benzhydrylglutaric acid 
• 124925-46-8 6a,12b-dihydro-6H,7H-benzo[c]phenanthrene-5,8-dione 
• 75-16-1 methylmagnesium bromide 
• 875843-81-5 5,8-dimethyl-5,6,6a,7,8,12b-hexahydro-benzo[c]phenanthrene 

Relevant articles and documents

Domino Friedel-crafts-type cyclizations of difluoroalkenes promoted by the α-cation-stabilizing effect of fluorine: An efficient method for synthesizing angular PAHs

In order to synthesize polycyclic aromatic hydrocarbons with nonlinear arrangements (angular PAHs), acid-promoted domino cyclizations of 1,1-difluoroalk-1-enes and 1,1-difluoroalka-1,3-dienes were studied. 1,1-Difluoroalkenes, each bearing two aryl substituents, were regioselectively protonated with FSO3H·SbF5 to generate fluorine-stabilized carbocations, which readily underwent domino Friedel-Crafts-type cyclizations to give carbocycles based on 6/n/m/6 ring systems (n,m=5-7) in good to high yields. Protonation of 1,1-difluoroalka-1,3- dienes took place at their electron-rich methylene (CH2) carbon atoms in the presence of milder acids such as camphorsulfonic acid and trifluoromethanesulfonic acid. Domino cyclizations of the resulting fluorine-stabilized allylic carbocations afford carbocycles based on 6/6/6/6 or 6/6/5/6 ring systems in high yields.