55000-07-2Relevant articles and documents
Chemoselective reduction of azides catalyzed by molybdenum xanthate by using phenylsilane as the hydride source
Maddani, Mahagundappa R.,Moorthy, Saravana K.,Prabhu, Kandikere R.
supporting information; experimental part, p. 329 - 333 (2010/03/01)
A chemoselective, neutral, and efficient strategy for the reduction of azides to corresponding amines catalyzed by dioxobis(N,N,-diethyldithiocarbamato) molybdenum complex (1, MoO2[S2CNEt2]2) in the presence of phenylsilane is discovered. This chemoselective reduction strategy tolerates a variety of reducible functional groups.