55262-10-7Relevant articles and documents
Synthesis of precursors of phomactins using [2,3]-Wittig rearrangements
Shapland, Peter D.P.,Thomas, Eric J.
experimental part, p. 4201 - 4211 (2009/09/27)
o-Toluic acid has been converted into methyl (8RS,9SR)-7-(bromomethyl)-8,9-dimethyl-1,4-dioxaspiro[4.5]dec-6-ene-8-carboxylate, the stereochemical defining step being a conjugate addition of lithium dimethylcuprate to a cyclohexadienone prepared using a B
Simple two-step ipso substitution of aromatic carboxylic acids by alkyl halides
Vorndran, Katja,Linker, Torsten
, p. 2489 - 2491 (2007/10/03)
Methyl-substituted arenes can be synthesized with high regioselectivity in only two steps through formal exchange of an aromatic carboxylic acid function with an alkyl substituent. The results obtained with toluic acid illustrate that good to very good yields can be obtained from inexpensive reagents (see scheme).
Regio- und diastereoselektive Photooxygenierung chiraler 2,5-Cyclohexadien-1-carbonsaeuren
Linker, Torsten,Froehlich, Lothar
, p. 2064 - 2066 (2007/10/02)
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