55287-54-2

Basic information

• Product Name: 3,4-di-O-benzyl-2-acetamido-2-desoxy-α-benzyl-D-glucopyranoside
• Synonyms: 3,4-di-O-benzyl-2-acetamido-2-desoxy-α-benzyl-D-glucopyranoside
• CAS NO: 55287-54-2
• Molecular Weight: 491.584
• Mol File: 55287-54-2.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 3,4-di-O-benzyl-2-acetamido-2-desoxy-α-benzyl-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: 3,4-di-O-benzyl-2-acetamido-2-desoxy-α-benzyl-D-glucopyranoside(55287-54-2)
• EPA Substance Registry System: 3,4-di-O-benzyl-2-acetamido-2-desoxy-α-benzyl-D-glucopyranoside(55287-54-2)

Safety Data

• Hazardous Substances Data: 55287-54-2(Hazardous Substances Data)

Upstream product

• 55287-53-1 benzyl 2-acetamido-3,4-di-O-benzyl-2-deoxy-6-O-trityl-α-D-gluco-pyranoside 
• 14146-27-1 benzyl 3-O-benzyl-2-acetamido-2-deoxy-α-D-glucopyranoside 
• 100-44-7 benzyl chloride 
• 66026-10-6 N-((4aR,6S,7R,8R,8aS)-6-(benzyloxy)-8-hydroxy-2,2-dimethylhexahydropyrano[3,2-d][1,3]dioxin-7-yl)acetamide 
• 67398-54-3 benzyl 2-acetamido-3-O-benzyl-2-deoxy-4,6-O-isopropylidene-α-D-glucopyranoside 
• 100-39-0 benzyl bromide 
• 13343-63-0 benzyl 4,6-O-benzylidene-2-acetylamino-2-deoxy-α-D-glucopyranoside 
• 14146-26-0 benzyl 2-acetamido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-α-D-glucopyranoside 
• 13343-62-9 benzyl 2-acetamido-2-deoxy-α-D-glucopyranoside 

Downstream Products

• 79548-56-4 benzyl 2-acetamido-3,4-di-O-benzyl-2-deoxy-6-O-(D-1-carboxyethyl)-α-D-glucopyranoside 
• 305834-20-2 benzyl 2-acetamido-3,4-di-O-benzyl-2,6-dideoxy-6-iodo-α-D-gluco-pyranoside 
• 305834-25-7 5-acetamido-3,4-di-O-benzyl-1,2,5-trideoxy-L-xylo-hex-1-enitol 
• 162843-31-4 benzyl 2-acetamido-3,4-di-O-benzyl-2-deoxy-6-O-(2-hydroxyethyl)-α-D-glucopyranoside 
• 41341-94-0 benzyl 2-acetamido-3,4-di-O-benzyl-2,6-dideoxy-6-fluoro-α-D-glucopyranoside 
• 75281-03-7 benzyl 2-acetamido-3,4-di-O-benzyl-6-O-(D-1-carboxyethyl)-2-deoxy-α-D-glucopyranoside 

Relevant articles and documents

Synthesis of C6-substituted UDP-GlcNAc derivatives

UDP-sugar analogs are useful for the study of glycosyltransferases and the production of unnatural glycans. The preparation of five UDP-GlcNAc derivatives is reported with 6-deoxy, 6-azido, 6-amino, 6-mercapto, or 6-fluoro substitutions. A concise chemoen

Preparation of O-Hydroxyethyl and O-Hydroxypropyl Derivatives of D-Glucose and 2-Acetamido-2-deoxy-D-glucose for Studies of Modified Hyaluronic Acid

Some hydroxyethyl and hydroxypropyl derivatives of D-glucose and of 2-acetamido-2-deoxy-D-glucose have been sunthesized for use as reference substances for structural studies of hydroxyethylated and hydroxypropylated hyaluronic acid.Hydroxyethyl and hydroxypropyl substituents were introduced in the 2-O- or 3-O-position of D-glucose and in the 4-O- or 6-O-positions of 2-acetamido-2-deoxy-D-glucose by reaction of suitably protected sugars with either ethylene oxide or propylene oxide.For hydroxyethyl derivatives yields varied between 21 and 74percent and with a substantial portion of the doubly alkylated compounds.For hydroxypropyl derivatives yields varied between 15 and 80percent.Only trace amounts of the doubly alkylated compounds were found.The proportions of the respective derivatives were estimated using GLC-MS.All products were characterized by 1H and 13C NMR spectroscopy.

APPROACHES TO THE SELECTIVE BENZYLATION OF THE PRIMARY HYDROXYL GROUP

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