55652-52-3 Usage
Description
MONOBROMOBORANE-METHYL SULFIDE COMPLEX is a chemical compound that serves as a versatile reagent in various chemical reactions. It is known for its ability to participate in substitution reactions, hydroboration reactions, and regioand chemoselective brominative cleavage of terminal epoxides.
Uses
Used in Chemical Synthesis:
MONOBROMOBORANE-METHYL SULFIDE COMPLEX is used as a reactant for substitution reactions for the synthesis of N-heterocyclic carbene boranes with boron-heteroatom bonds. This application is valuable in the creation of new compounds with specific properties and potential applications in various industries.
Used in Hydroboration Reactions:
In the field of organic chemistry, MONOBROMOBORANE-METHYL SULFIDE COMPLEX is utilized as a reactant in hydroboration reactions. These reactions are essential for the formation of various organic compounds, making it a crucial component in the synthesis process.
Used in Regioand Chemoselective Brominative Cleavage of Terminal Epoxides:
MONOBROMOBORANE-METHYL SULFIDE COMPLEX is employed as a reactant for the regioand chemoselective brominative cleavage of terminal epoxides. This selective cleavage is vital in the synthesis of specific compounds with desired properties, making it an important tool in the chemical industry.
Check Digit Verification of cas no
The CAS Registry Mumber 55652-52-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,5,6,5 and 2 respectively; the second part has 2 digits, 5 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 55652-52:
(7*5)+(6*5)+(5*6)+(4*5)+(3*2)+(2*5)+(1*2)=133
133 % 10 = 3
So 55652-52-3 is a valid CAS Registry Number.
55652-52-3Relevant articles and documents
Facile Synthesis of a Stable Dihydroboryl {BH2}? Anion
Arrowsmith, Merle,Mattock, James D.,Hagspiel, Stephan,Krummenacher, Ivo,Vargas, Alfredo,Braunschweig, Holger
, p. 15272 - 15275 (2018)
While the one-electron reduction of (CAACMe)BH2Br (CAACMe=1-(2,6-diisopropylphenyl)-3,3,5,5-tetramethylpyrrolidin-2-ylidene) yields a hydride-shift isomer of the corresponding tetrahydrodiborane, a further reversible reduction leads to the first stable parent boryl anion, [(CAACMe)BH2]?, which acts as a powerful boron nucleophile.
