5581-75-9Relevant articles and documents
Evidence for the involvement of silver nanoclusters during the wolff rearrangement of α-diazoketones
Sudrik, Surendra G.,Maddanimath, Trupti,Chaki, Nirmalya K.,Chavan, Sambhaji P.,Chavan, Subhash P.,Sonawane, Harikisan R.,Vijayamohanan
, p. 2355 - 2358 (2003)
(Matrix presented) In situ-generated silver nanoclusters(Agn) during the reduction of either silver(I) oxide or other salts presumably catalyze the Wolff rearrangement of α-diazoketones. Their optical, physical, and catalytic properties depend
Site-Selective, Remote sp3 C?H Carboxylation Enabled by the Merger of Photoredox and Nickel Catalysis
Sahoo, Basudev,Bellotti, Peter,Juliá-Hernández, Francisco,Meng, Qing-Yuan,Crespi, Stefano,K?nig, Burkhard,Martin, Ruben
supporting information, p. 9001 - 9005 (2019/06/24)
A photoinduced carboxylation of alkyl halides with CO2 at remote sp3 C?H sites enabled by the merger of photoredox and Ni catalysis is described. This protocol features a predictable reactivity and site selectivity that can be modulated by the ligand backbone. Preliminary studies reinforce a rationale based on a dynamic displacement of the catalyst throughout the alkyl side chain.
CARBOXAMIDE INHIBITORS
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Paragraph 0395-0397, (2017/08/01)
The present invention provides a compound of formula I The compounds of formula I demonstrate properties as Smurf-1 inhibitors and are thus useful in the treatment of a range of disorders, particularly pulmonary arterial hypertension.