55898-33-4

Basic information

• Product Name: lysocellin
• Synonyms: lysocellin
• CAS NO: 55898-33-4
• Molecular Formula: C34H60O10
• Molecular Weight: 628.838
• Mol File: 55898-33-4.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 586.1°C (rough estimate)
• Flash Point: 216°C
• Appearance: /
• Density: 1.0683 (rough estimate)
• Vapor Pressure: 3.98E-24mmHg at 25°C
• Refractive Index: 1.5376 (estimate)
• PKA: 4.38±0.10(Predicted)
• CAS DataBase Reference: lysocellin(CAS DataBase Reference)
• NIST Chemistry Reference: lysocellin(55898-33-4)
• EPA Substance Registry System: lysocellin(55898-33-4)

Safety Data

• Hazardous Substances Data: 55898-33-4(Hazardous Substances Data)

Usage

InChI:InChI=1/C34H60O10/c1-11-24(29(38)22(8)28(37)23(9)30-19(5)14-18(4)25(41-30)15-27(36)43-40)31-20(6)16-32(10,42-31)34(39)21(7)17-33(13-3,44-34)26(35)12-2/h18-26,28,30-31,35,37,39-40H,11-17H2,1-10H3/t18-,19+,20+,21-,22+,23?,24+,25+,26+,28-,30+,31?,32+,33-,34-/m1/s1

Upstream product

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• 144534-79-2 2-<(2S,3R,5S,6S)-3,5-dimethyl-2-hydroxy-6-<(2S)-1-oxoprop-2-yl>tetrahydropyran-2-yl>acetic acid 
• 144534-92-9 (4R,5S)-5-Ethyl-4-((R)-2-iodo-1-methyl-ethyl)-2,2-dimethyl-[1,3]dioxane 
• 152934-39-9 (2S)-2-<(4S,5S)-5-Ethyl-2,2-dimethyl-1,2-dioxan-4-yl>propan-1-ol 
• 144535-01-3 (1R,2R,4R,5S)-5-Benzyloxy-4-ethyl-1-[(2S,4S,5S)-5-((S)-1-ethyl-2-hydroxy-butyl)-2,4-dimethyl-tetrahydro-furan-2-yl]-2-methyl-heptane-1,4-diol 
• 144534-80-5 (2S,3R,5R,6S)-6-Benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-5-ethyl-2-(4-methoxy-benzyloxy)-3-methyl-octanal 
• 173044-02-5 (2S,3S,4S)-5-{(2R,3R)-3-[(1R,3R,4S)-4-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-3-ethyl-1-methyl-hexyl]-2-methyl-oxiranyl}-2-ethyl-4-methyl-pentane-1,3-diol 
• 173044-03-6 (1R,2R,4R,5S)-5-Benzyloxy-4-(tert-butyl-dimethyl-silanyloxy)-4-ethyl-1-[(2S,4S,5S)-5-((S)-1-hydroxymethyl-propyl)-2,4-dimethyl-tetrahydro-furan-2-yl]-2-methyl-heptan-1-ol 
• 144535-00-2 Acetic acid (1R,2R,4R,5S)-5-benzyloxy-4-(tert-butyl-dimethyl-silanyloxy)-4-ethyl-1-[(2S,4S,5S)-5-((S)-1-hydroxymethyl-propyl)-2,4-dimethyl-tetrahydro-furan-2-yl]-2-methyl-heptyl ester 
• 173044-08-1 (1R,2R,4R,5S)-5-Benzyloxy-4-(tert-butyl-dimethyl-silanyloxy)-1-{(2S,4S,5S)-5-[(S)-1-(tert-butyl-dimethyl-silanyloxymethyl)-propyl]-2,4-dimethyl-tetrahydro-furan-2-yl}-4-ethyl-2-methyl-heptan-1-ol 
• 173044-10-5 Acetic acid (1R,2R,4R,5S)-5-benzyloxy-4-(tert-butyl-dimethyl-silanyloxy)-4-ethyl-1-[(2S,4S,5S)-5-((R)-1-formyl-propyl)-2,4-dimethyl-tetrahydro-furan-2-yl]-2-methyl-heptyl ester 
• 173044-09-2 Acetic acid (1R,2R,4R,5S)-5-benzyloxy-4-(tert-butyl-dimethyl-silanyloxy)-1-{(2S,4S,5S)-5-[(S)-1-(tert-butyl-dimethyl-silanyloxymethyl)-propyl]-2,4-dimethyl-tetrahydro-furan-2-yl}-4-ethyl-2-methyl-heptyl ester 
• 144534-97-4 Methanesulfonic acid (1S,2R,4R,5S)-5-benzyloxy-4-(tert-butyl-dimethyl-silanyloxy)-4-ethyl-1-[(1S,3S)-3-((4S,5S)-5-ethyl-2,2-dimethyl-[1,3]dioxan-4-yl)-1-hydroxy-1-methyl-butyl]-2-methyl-heptyl ester 
• 144534-95-2 (2S,5S,6R,8R,9S)-9-Benzyloxy-8-(tert-butyl-dimethyl-silanyloxy)-8-ethyl-2-((4S,5S)-5-ethyl-2,2-dimethyl-[1,3]dioxan-4-yl)-5-(4-methoxy-benzyloxy)-6-methyl-undecan-4-ol 

Relevant articles and documents

Total Synthesis of the Polyether Antibiotic Lysocellin. 2. Stereocontrolled Synthesis of the C10-C23 Fragment and Its Aldol Condensation with the C1-C9 Fragment to Complete the Total Synthesis of Lysocellin

The C10-C23 ethyl ketone (4) was synthesized via coupling of the C16-C23 aldehyde (3) with the C11-C15 fragment (8), and subjected to the aldol reaction with the C1-C9 aldehyde (2) to complete the first stereoselective synthesis of the polyether antibioti