559-45-5Relevant articles and documents
An unprecedented elimination-driven migration: The reductive dihalobornane-camphene rearrangement
Garamszegi, Laszlo,Schlosser, Manfred
, p. 3173 - 3175 (2007/10/03)
An organometallic counterpart of the Wagner-Meerwein rearrangement, the incarnation of an carbocationic alkyl 1,2-migration, has now been discovered. However, the structural reorganization does not occur through carbanionic intermediates, but can only be brought about by a push-pull process via 1a (see scheme).