56923-15-0

Basic information

• Product Name: 2-Cyclohexen-1-one, 2-phenyl-, oxime
• CAS NO: 56923-15-0
• Molecular Formula: C12H13NO
• Molecular Weight: 187.241
• Mol File: 56923-15-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-Cyclohexen-1-one, 2-phenyl-, oxime(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Cyclohexen-1-one, 2-phenyl-, oxime(56923-15-0)
• EPA Substance Registry System: 2-Cyclohexen-1-one, 2-phenyl-, oxime(56923-15-0)

Safety Data

• Hazardous Substances Data: 56923-15-0(Hazardous Substances Data)

Upstream product

• 771-98-2 1-Phenylcyclohexene 
• 56923-11-6 1e-phenyl-1a-chloro-2a-nitrosocyclohexane (dimer) 
• 4556-09-6 2-phenylcyclohex-2-enone 

Downstream Products

• 80738-31-4 <(1S*,2R*)-3-oxo-2-phenylcyclohexyl>acetic acid 
• 7404-97-9 2-(benzoylamino)biphenyl 
• 2720-93-6 6-phenylphenanthridine 
• 36567-45-0 trans-2e-Phenyl-3e-(4-methylphenyl)-cyclohexanone 
• 89524-55-0 trans-2e-Phenyl-3e-benzylcyclohexanone 
• 36567-43-8 trans-2,3-diphenylcyclohexan-1-one 
• 84211-18-7 2,4-dinitrophenylhydrazone of 2e,3e-diphenylcyclohexanone 
• 84211-25-6 semicarbazone of 2e-phenyl-3e-benzylcyclohexanone 
• 84211-17-6 semicarbazone of 2e,3e-diphenylcyclohexanone 
• 84211-19-8 O-acetylated oxime of 2e,3e-diphenylcyclohexanone 
• 84211-20-1 O-methyloxime of 2e,3e-diphenylcyclohexanone 
• 84211-24-5 semicarbazone of 2e-phenyl-3e-ethylcyclohexanone 
• 84211-13-2 oxime of 2e-phenyl-3e-benzylcyclohexanone 
• 84211-16-5 hydrazone of 2e,3e-diphenylcyclohexanone 

Relevant articles and documents

Pd-catalyzed Semmler-Wolff reactions for the conversion of substituted cyclohexenone oximes to primary anilines

Homogeneous Pd catalysts have been identified for the conversion of cyclohexenone and tetralone O-pivaloyl oximes to the corresponding primary anilines and 1-aminonaphthalenes. This method is inspired by the Semmler-Wolff reaction, a classic method that exhibits limited synthetic utility owing to its forcing conditions, narrow scope, and low product yields. The oxime N-O bond undergoes oxidative addition to Pd0(PCy3)2, and the product of this step has been characterized by X-ray crystallography and shown to undergo dehydrogenation to afford the aniline product.