57103-17-0Relevant articles and documents
The twisted structure of 9-(4-cyanophenyl)-carbazole
Saha, Satyen,Samanta, Anunay
, p. 1299 - 1300 (1999)
The crystal structure determination of the title compound, C19H12N2, has been undertaken with a view to understanding the nature of the fluorescence band of the system. There is a significant twist between the cyanophenyl and carbazolyl moieties.
Synthesis and properties of blue luminescent bipolar materials constructed with carbazole and anthracene units with 4-cyanophenyl substitute at the 9-position of the carbazole unit
Xie, Pengbo,Yuan, Ningning,Li, Shanji,Ouyang, Ying,Zhu, Yongju,Liang, Hui
, p. 604 - 610 (2018)
With carbazole and p-cyanobromobenzene as raw materials, 4-(3,6-di (anthracen-9-yl)-9H-carbazol-9-yl)benzonitrile (DACB) and 4-(3,6-bis(anthracene -9-ylethynyl)-9H-carbazol-9-yl)benzonitrile (BACB) were synthesized through the Suzuki coupling reaction and
Microenvironment modulation of cuprous cluster enables inert aryl chlorides activation in single-molecule metallaphotoredox amination
Ji, Wei,Jing, Su,Li, Ai-Min,Qi, Zheng-Hang,Qiu, Wen-Jie,Zha, Guo-Jin,Zhu, Dun-Ru
, p. 313 - 321 (2022/01/03)
Amination of aryl halides is an important tool in organic synthesis and the activation of inert aryl chlorides is particular difficult. We herein report the first study of aromatic microenvironment modulation of cuprous clusters as single-molecule metalla
Method for synthesizing carbazole derivative
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Paragraph 0013; 0046-0047, (2021/10/05)
The invention aims to provide a method for synthesizing a carbazole derivative. The method is characterized in that palladium chloride is used as a catalyst, 2, 2' - dibromobiphenyl is used as an electrophilic reagent, primary amine is taken as a nucleophile, and the carbazole derivative is directly cross-coupled under the conditions of toluene as a solvent and an air atmosphere. The method has the advantages of high yield, high selectivity, simplicity and convenience in operation and the like.
Palladium-Catalyzed Cyanation of Aryl Halides Using Formamide and Cyanuric Chloride as a New “CN” Source
Niknam, Esmaeil,Panahi, Farhad,Khalafi-Nezhad, Ali
, p. 2699 - 2707 (2020/04/08)
A new source of “CN” employing formamide and cyanuric chloride is introduced for the cyanation reactions. The treatment of formamide and 2,4,6-trichloro-1,3,5-triazine (TCT; cyanuric chloride) afforded an efficient cyanating agent which it can be used as a nontoxic, readily available, and non-expensive reagent in the cyanation transformations. In this study, palladium-catalyzed cyanation of aryl halides was successfully accomplished using this new “CN” source in high yields.