57197-26-9Relevant articles and documents
Metal-free direct: C -arylation of 1,3-dicarbonyl compounds and ethyl cyanoacetate: A platform to access diverse arrays of meta -functionalized phenols
Taneja, Neha,Peddinti, Rama Krishna
supporting information, p. 11423 - 11426 (2018/10/20)
A base mediated, highly convenient strategy for the direct C-arylation of 1,3-dicarbonyls and cyanoacetate with various phenol derivatives as aryl partners is presented. The present work excels in forming a C-C bond at the meta-position of the phenols, which is traditionally challenging to functionalize. This protocol further leads the way to have scalable, straightforward access to phenol assimilated heterocycles which have powerful applications both in synthetic chemistry and medicinal research.
α-Halogenation as a Strategy to Functionalize Cyclohexa-2,4-dienones
Chittimalla, Santhosh Kumar,Koodalingam, Manikandan,Gadi, Vinod Kumar,Anaspure, Prasad
supporting information, p. 475 - 480 (2017/02/24)
A facile pyridine-mediated α-halogenation approach to functionalize cyclohexa-2,4-dienones is developed. A range of reactions, including organometallic coupling protocols, have been applied on these newly obtained halogenated cyclohexa-2,4-dienones, and the results are presented herein.
Substituent effect on di-π-methane reactions of benzopyrazinobarrelenes and benzoquinoxalinobarrelenes
Chuang, Gary J.,Liao, Chun-Chen
supporting information, p. 1301 - 1315 (2017/02/15)
To examine the substituent effect on the di-π-methane (DPM) rearrangement of barrelene-like skeleton, benzopyrazinobarrelene (BPB) and benzoquinoxalinobarrelene (BQB) were utilized as the photoreaction experimental platforms. By the installation of the py
