57205-10-4Relevant articles and documents
Synthetic efforts toward the bicyclo[3.2.1]octane fragment of rhodojaponin III
Webster, Caroline G.,Park, Hyeri,Ennis, Amanda F.,Hong, Jiyong
supporting information, (2021/04/22)
Rhodojaponin III is a grayanane-type diterpenoid natural product with a novel chemical scaffold. It shows potent antinociceptive activity and may represent a new class of natural non-opioid analgesics with a novel mode of action. We explored the Au(I)-cat
Odorless diphenyl diselenide and disulfide: Syntheses and applications
Patra, Pranab K.,Shanmugasundaram, Kandasamy,Matoba, Manabu,Nishide, Kiyoharu,Kajimoto, Tetsuya,Node, Manabu
, p. 447 - 457 (2007/10/03)
Bis[4-(trimethylsilyl)phenyl]diselenide (3) and bis[4-(trimethylsilyl) phenyl]disulfide (31) are found to be odorless equivalents of the commonly used diphenyl diselenide and diphenyl disulfide, respectively. The diselenide 3 is shown to be useful in the preparation of odorless selenium(II) chloride 26 and selenium(IV) trichloride 28 that follow similar reactivity patterns to their phenyl derivatives and can be stored refrigerated under dry conditions. The corresponding selenium(II) bromide had to be prepared fresh from 3 before use. It is also shown that the trimethylsilyl group in the sulfide products can be protodesilylated quantitatively using TFA. Georg Thieme Verlag Stuttgart.
A FACILE ACCESS TO α-PHENYLSELENENYL CARBONYL COMPOUNDS BY ELECTROCHEMICAL OXIDATION
Torii, Sigeru,Uneyama, Kenji,Handa, Ko
, p. 1863 - 1866 (2007/10/02)
A novel α-phenylselenenylation of carbonyl compounds has been performed by electrolysis of a solution of ketones, diphenyl diselenide, tetraethyl-ammonium bromide, and magnesium bromide in polar solvents (MeOH, AcOH, MeCN).The electrolysis enables us to p
