5751-32-6

Basic information

• Product Name: 2-[(1E)-3-phenylprop-1-en-1-yl]naphthalene
• Synonyms: 2-[(1E)-3-phenylprop-1-en-1-yl]naphthalene
• CAS NO: 5751-32-6
• Molecular Weight: 244.336
• Mol File: 5751-32-6.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: 2-[(1E)-3-phenylprop-1-en-1-yl]naphthalene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-[(1E)-3-phenylprop-1-en-1-yl]naphthalene(5751-32-6)
• EPA Substance Registry System: 2-[(1E)-3-phenylprop-1-en-1-yl]naphthalene(5751-32-6)

Safety Data

• Hazardous Substances Data: 5751-32-6(Hazardous Substances Data)

Upstream product

• 776296-19-6 3-(2-naphthyl)-2-propenyl methyl carbonate 
• 100-58-3 phenylmagnesium bromide 
• 300-57-2 allylbenzene 
• 1503-86-2 2-naphthyl pivalate 
• 135-19-3 β-naphthol 
• 103-63-9 1-phenyl-2-bromoethane 
• 66-99-9 β-naphthaldehyde 
• 1014394-68-3 (E)-3-(naphthalen-2-yl)allyl pivalate 
• 61124-61-6 3-phenylpropanal p-tosylhydrazone 
• 42096-34-4 naphthalen-2-yl 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate 
• 143-66-8 sodium tetraphenyl borate 
• 115117-86-7 (2E)-3-(2-naphthyl)prop-2-en-1-yl acetate 
• 100-52-7 benzaldehyde 
• 93-08-3 methyl 2-naphthyl ketone 

Relevant articles and documents

Olefination with Sulfonyl Halides and Esters: Scope, Limitations, and Mechanistic Studies of the Hawkins Reaction

Carbanions of alkanesulfonyl halides and esters react with nonenolizable carbonyl compounds to give olefins. Mechanistic studies reveal that initial aldol-type addition of the carbanions is followed by cyclization-fragmentation to alkenes, and the leaving group on the sulfonyl moiety (RSO2X) controls carbanion stability and rate of the olefin formation.

S,O-ligand-promoted palladium-catalyzed C–H olefination of arenes with allylic substrates

An efficient catalytic system for the C–H olefination of arenes with different allylic substrates is reported. The catalytic system is based on Pd(OAc)2 and a readily accessible bidentate S,O-ligand. The methodology shows high activity with a wide range of arenes, including bulky and, electron-rich and -poor arenes. The applicability of this catalyst is demonstrated in the late-stage functionalization of the complex molecule O-methylestrone.

A palladium NNC-pincer complex: An efficient catalyst for allylic arylation at parts per billion levels

Allylic arylation of allylic acetates by sodium tetraarylborates in the presence of ppb to ppm (molar) loadings of a palladium NNC-pincer complex catalyst in methanol at 50°C gave the corresponding arylated products in excellent yields. Total turnover numbers of up to 500 000 000 and turnover frequencies of up to 11 250 000 h-1 were achieved.