577974-19-7

Basic information

• Product Name: (2S)-2-tert-butoxycarbonylamino-4-oxo-4-(3-nitrophenyl)butyric acid ethyl ester
• Synonyms: (2S)-2-tert-butoxycarbonylamino-4-oxo-4-(3-nitrophenyl)butyric acid ethyl ester
• CAS NO: 577974-19-7
• Molecular Weight: 366.371
• Mol File: 577974-19-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2S)-2-tert-butoxycarbonylamino-4-oxo-4-(3-nitrophenyl)butyric acid ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (2S)-2-tert-butoxycarbonylamino-4-oxo-4-(3-nitrophenyl)butyric acid ethyl ester(577974-19-7)
• EPA Substance Registry System: (2S)-2-tert-butoxycarbonylamino-4-oxo-4-(3-nitrophenyl)butyric acid ethyl ester(577974-19-7)

Safety Data

• Hazardous Substances Data: 577974-19-7(Hazardous Substances Data)

Upstream product

• 85992-86-5 2-Brom-2-(tert-butoxycarbonylamino)essigsaeure-ethylester 
• 14719-37-0 ethyl 2-(tert-butoxycarbonylamino)acetate 
• 81357-11-1 [(E)-tert-Butoxycarbonylimino]-acetic acid ethyl ester 
• 74812-78-5 1-(m-nitrophenyl)-1-(trimethylsilyloxy)ethylene 

Relevant articles and documents

Catalytic, asymmetric Mannich-type reactions of α-imino esters bearing readily removable substituents on nitrogen

(Matrix presented) Catalytic, enantioselective Mannich-type reactions of α-imino esters bearing readily removable substituents on nitrogen are described. Several N-carbamate-protected α-imino esters, which are readily prepared from 2-bromoglycine esters using a polymer-supported amine, reacted with silicon enolates to afford the desired adducts in high yields with high enantioselectivity using a copper(II)-diamine complex. Easy deprotection of the product amine and transformation to free o-amino acid derivatives have also been demonstrated.