57981-61-0

Basic information

• Product Name: (Z,E)-trideca-4,7-dien-1-ol
• Synonyms: (Z,E)-trideca-4,7-dien-1-ol;(4E,7Z)-4,7-Tridecadien-1-ol;(4Z,7E)-4,7-Tridecadien-1-ol;4,7-Tridecadien-1-ol, (4E,7Z)-;Einecs 261-059-8;(E,Z)-4,7-tridecadienol;4E7Z-13OH;trans-4,cis-7-tridecadien-1-ol
• CAS NO: 57981-61-0
• Molecular Formula: C₁₃H₂₄O
• Molecular Weight: 196.32906
• EINECS: 261-059-8
• Mol File: 57981-61-0.mol
• Article Data: 17

Chemical Properties

• Boiling Point: 295.1 °C at 760 mmHg
• Flash Point: 109.3 °C
• Appearance: /
• Density: 0.861 g/cm³
• Vapor Pressure: 0.000163mmHg at 25°C
• Refractive Index: 1.473
• PKA: 15.06±0.10(Predicted)
• CAS DataBase Reference: (Z,E)-trideca-4,7-dien-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (Z,E)-trideca-4,7-dien-1-ol(57981-61-0)
• EPA Substance Registry System: (Z,E)-trideca-4,7-dien-1-ol(57981-61-0)

Safety Data

• Hazardous Substances Data: 57981-61-0(Hazardous Substances Data)

Usage

General Description

(Z,E)-trideca-4,7-dien-1-ol is a chemical compound with the molecular formula C13H24O. It is a long-chain, unsaturated alcohol consisting of a carbon chain with a double bond at the 4th and 7th carbon positions, with a trans configuration at the 4th carbon and a cis configuration at the 7th carbon. (Z,E)-trideca-4,7-dien-1-ol is commonly found in natural sources such as plants and insects and is often used in the production of perfumes and flavors due to its pleasant odor and taste. It also has potential applications in the pharmaceutical and cosmetic industries due to its biological activities and properties.

InChI:InChI=1/C13H24O/c1-2-3-4-5-6-7-8-9-10-11-12-13-14/h6-7,9-10,14H,2-5,8,11-13H2,1H3/b7-6+,10-9-

Upstream product

• 33821-94-2 3-(tetrahydro-2H-pyran-2-yloxy)propyl bromide 
• 132124-56-2 (1E,4Z)-1-Bromo-deca-1,4-diene 
• 56722-26-0 1-bromo-(2E,5Z)-2,5-undecadiene 
• 101020-37-5 ethyl 2-carbethoxy-(4E,7Z)-4,7-tridecadienoate 
• 168422-43-3 methyl ester of 7Z-tridecene-4-in-1-oic acid 
• 139269-70-8 (4E,7Z)-1-(tetrahydropyran-2-yloxy)trideca-4,7-diene 
• 107691-98-5 (Z)-7-tridecen-4-yn-1-ol 
• 124381-46-0 (4E,7Z)-4,7-tridecadienal 
• 68236-05-5 ethyl 4(E),7(Z)-tridecadienoate 
• 89682-47-3 (3Z)-3-nonenal diethyl acetal 
• 90290-02-1 3-nonynal diethyl acetal 
• 31823-43-5 (Z)-3-nonenal 
• 628-71-7 1-Heptyne 
• 112182-98-6 2-(1-Vinyl-non-3-ynyloxy)-tetrahydro-pyran 

Downstream Products

• 57981-60-9 (4E,7Z)-4,7-tridecadien-1-yl acetate 
• 68236-06-6 (4Z,7Z)-4,7-Tridecadien-1-yl acetate 

Relevant articles and documents

Nonconjugated Dienes from 1-Alkenes: Application to the Synthesis of Sex Pheromone (4E,7Z)-4,7-Tridecadienyl Acetate

(4E,7Z)-4,7-Tridecadienyl acetate 1, a component of the sex pheromone was synthesized from 5-hexenyl acetate. (E)-γ,δ-Unsaturated phosphonate as the key intermediate afforded a target molecule, using the Horner-Wadsworth-Emmons (HWE) reaction and desulfonylation as the main process.

Insect pheromones and their analogs LV. Synthesis of trideca-4E,7Z-dien-1-yl acetate - Component of the sex pheromone of Phthorimaea opercucella

Starting from propargyl alcohol and using the thermal Claisen rearrangement at the stage of constructing the (E)-double bond, we have synthesized trideca-4E, 7Z-dien-1-yl acetate - a component of the sex pheromone of the potato moth Phthorimaea opercucella (Zeller).

Stereoselective Synthesis of 1,4-Dienes. Application to the Preparation of Insect Pheromones (3Z,6Z)-Dodeca-3,6-dien-1-ol and (4E,7Z)-Trideca-4,7-dienyl Acetate

Stereoselective synthesis of Z,E- and Z,Z-1,4-dienes has been achieved by the cross-coupling of allylic substrates with vinyl organometallic reagents.Key to this strategy was the development of a method for regiospecific incorporation of a tri-n-butylstannyl group in the γ-position of the allylic cross-coupling partner.The steric bulk of this moiety ensures the stereochemical integrity of the allylic double bond throughout the coupling sequence and is easily replaced by hydrogen in the coupled product.This strategy has been applied to the synthesis of the termite trail marker pheromone 22 and the leafminer moth sex pheromone 28.