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586-38-9

586-38-9

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586-38-9 Usage

Chemical Properties

Different sources of media describe the Chemical Properties of 586-38-9 differently. You can refer to the following data:
1. white to light yellow crystal powder
2. 3-Methoxybenzoic acid is practically odorless.

Uses

3-Methoxybenzoic acid is used in the synthesis and characterization of 3-methoxybenzoates of europium (III) and gadolinium (III)1. It was used in conversion of aromatic carboxylic acids into methyl esters and reduction to the corresponding primary alcohols using a sodium borohydride-THF-methanol system

General Description

3-Methoxybenzoic acid is an important intermediate in the synthesis of natural products.

Safety Profile

Poison by intraperitoneal route.When heated to decomposition it emits acrid smoke andirritating fumes.

Purification Methods

Crystallise m-anisic acid from H2O (m 109o, 110.5o) or EtOH/water. The S-benzylisothiuronium salt has m 176o (from EtOH). [Beilstein 10 II 80, 10 III 244, 10 IV 316.]

Check Digit Verification of cas no

The CAS Registry Mumber 586-38-9 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 5,8 and 6 respectively; the second part has 2 digits, 3 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 586-38:
(5*5)+(4*8)+(3*6)+(2*3)+(1*8)=89
89 % 10 = 9
So 586-38-9 is a valid CAS Registry Number.
InChI:InChI=1/C8H8O3/c1-11-7-4-2-3-6(5-7)8(9)10/h2-5H,1H3,(H,9,10)/p-1

586-38-9 Well-known Company Product Price

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  • Alfa Aesar

  • (A10767)  3-Methoxybenzoic acid, 99%   

  • 586-38-9

  • 50g

  • 565.0CNY

  • Detail

  • Alfa Aesar

  • (A10767)  3-Methoxybenzoic acid, 99%   

  • 586-38-9

  • 250g

  • 1422.0CNY

  • Detail

  • Alfa Aesar

  • (A10767)  3-Methoxybenzoic acid, 99%   

  • 586-38-9

  • 1000g

  • 4815.0CNY

  • Detail

586-38-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 3-Methoxybenzoic acid

1.2 Other means of identification

Product number -
Other names m-methoxybenzoic acid

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Food additives -> Flavoring Agents
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:586-38-9 SDS

586-38-9Relevant articles and documents

Mechanochemical Grignard Reactions with Gaseous CO2 and Sodium Methyl Carbonate**

Pfennig, Victoria S.,Villella, Romina C.,Nikodemus, Julia,Bolm, Carsten

supporting information, (2022/01/22)

A one-pot, three-step protocol for the preparation of Grignard reagents from organobromides in a ball mill and their subsequent reactions with gaseous carbon dioxide (CO2) or sodium methyl carbonate providing aryl and alkyl carboxylic acids in up to 82 % yield is reported. Noteworthy are the short reaction times and the significantly reduced solvent amounts [2.0 equiv. for liquid assisted grinding (LAG) conditions]. Unexpectedly, aryl bromides with methoxy substituents lead to symmetric ketones as major products.

Combining photoredox catalysis and oxoammonium cations for the oxidation of aromatic alcohols to carboxylic acids

Nandi, Jyoti,Hutcheson, Ellen L.,Leadbeater, Nicholas E.

supporting information, (2020/12/25)

A methodology is reported for converting alcohols to the corresponding carboxylic acids. A dual catalytic system involving a merger of photoredox catalysis and 4-acetamido-TEMPO is employed to carry out this oxidation process.

One-Pot Direct Oxidation of Primary Amines to Carboxylic Acids through Tandem ortho-Naphthoquinone-Catalyzed and TBHP-Promoted Oxidation Sequence

Kim, Hun Young,Oh, Kyungsoo,Si, Tengda

supporting information, p. 18150 - 18155 (2021/12/09)

Biomimetic oxidation of primary amines to carboxylic acids has been developed where the copper-containing amine oxidase (CuAO)-like o-NQ-catalyzed aerobic oxidation was combined with the aldehyde dehydrogenase (ALDH)-like TBHP-mediated imine oxidation protocol. Notably, the current tandem oxidation strategy provides a new mechanistic insight into the imine intermediate and the seemingly simple TBHP-mediated oxidation pathways of imines. The developed metal-free amine oxidation protocol allows the use of molecular oxygen and TBHP, safe forms of oxidant that may appeal to the industrial application.

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