58711-32-3

Basic information

• Product Name: 1-ethyl-2-oxocyclohexaneacetic acid methyl ester
• Synonyms: 1-ethyl-2-oxocyclohexaneacetic acid methyl ester
• CAS NO: 58711-32-3
• Molecular Weight: 198.262
• Mol File: 58711-32-3.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: 1-ethyl-2-oxocyclohexaneacetic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 1-ethyl-2-oxocyclohexaneacetic acid methyl ester(58711-32-3)
• EPA Substance Registry System: 1-ethyl-2-oxocyclohexaneacetic acid methyl ester(58711-32-3)

Safety Data

• Hazardous Substances Data: 58711-32-3(Hazardous Substances Data)

Upstream product

• 4423-94-3 2-ethylcyclohexanone 
• 96-32-2 bromoacetic acid methyl ester 
• 3274-96-2 2-ethylcyclohexanol 
• 58711-07-2 1-ethyl-2-oxocyclohexaneacetic acid 
• 74-88-4 methyl iodide 

Downstream Products

• 103012-99-3 1-ethyl-2-oxocyclohex-3-eneacetic acid methyl ester 
• 115867-83-9 1-ethyl-2-oxo-4(phenylmethyl)cyclohexaneacetic acid methyl ester 
• 112126-57-5 [(1S,4S)-1-Ethyl-4-(2-methyl-allyl)-2-oxo-cyclohexyl]-acetic acid methyl ester 
• 112126-57-5 [(1S,4R)-1-Ethyl-4-(2-methyl-allyl)-2-oxo-cyclohexyl]-acetic acid methyl ester 
• 106464-30-6 ((1S,4S)-4-Allyl-1-ethyl-2-oxo-cyclohexyl)-acetic acid methyl ester 
• 106464-30-6 ((1S,4R)-4-Allyl-1-ethyl-2-oxo-cyclohexyl)-acetic acid methyl ester 

Relevant articles and documents

Substituted 2-oxocyclohexaneacetic acid esters

Process for the production of substituted 2-oxocyclohexaneacetic acid esters and intermediates used for their production. The substituted 2-oxocyclohexaneacetic acid esters are themselves useful intermediates for the manufacture of substituted 2,3,4,9-tet

Substituted 2,3,4,9-tetrahydro-1H-carbazole-1-acetic acid

Substituted 2,3,4,9-tetrahydro-1H-carbazole-1-acetic acid derivatives and methods for their preparation and use are disclosed. The compounds are useful analgesic and antiinflammatory agents.

1,4-DIASTEREOSELECTIVITY IN THE ADDITION OF ALLYLSTANNANES TO 1-ALKYL-2-OXOCYCLOHEX-3-ENEACETIC ACID METHYL ESTERS

Cyclohexanones 1 were allowed to react with allyltrimethylsilane and three allyltributylstannanes in the presence of titanium tetrachloride.Products 2 and 3 were formed in ratios ranging from 7:1 to 26:1 (2:3).Ratios resulting from the use of other Lewis acids support 4 as an intermediate which accounts for the observed stereoselectivity.