58927-78-9Relevant articles and documents
Silica gel-mediated rearrangement of allylic acetates. Application to the synthesis of 1,3-enynes
Serra-Muns, Anna,Guerinot, Amandine,Reymond, Sebastien,Cossy, Janine
supporting information; experimental part, p. 4178 - 4180 (2010/08/07)
Silica gel was found to efficiently promote the rearrangement of allylic acetates into their most stable regioisomers under microwave irradiation. The reaction is easy to perform and eco-friendly. This method was applied to the metal-free synthesis of 1,3-enynes.