59121-64-1Relevant articles and documents
Synthesis of oxygenated 4-arylisoflavans and 4-arylflavans
Deodhar, Mandar,Wood, Kasey,Black, David Stc,Kumar, Naresh
, p. 6697 - 6700,4 (2012)
Oxygenated 4-arylisoflavans and 4-heteroarylisoflavans were synthesized in good yields via BF3·OEt2 catalyzed arylation reactions of 4′,7-diacetoxyisoflavan-4-ol 8 with activated aryl and heteroaryl compounds. These reactions were found to produce stereoselectively the trans isomers. Similar reactions of 4′,7-diacetoxyflavan-4-ol 16 afforded the corresponding 4-arylflavans and 4-heteroarylflavans as mixtures of cis/trans isomers.
Synthesis of oxygenated 4-arylisoflavans and 4-arylflavans
Deodhar, Mandar,Wood, Kasey,Black, David Stc,Kumar, Naresh
, p. 6697 - 6700 (2013/01/15)
Oxygenated 4-arylisoflavans and 4-heteroarylisoflavans were synthesized in good yields via BF3·OEt2 catalyzed arylation reactions of 4′,7-diacetoxyisoflavan-4-ol 8 with activated aryl and heteroaryl compounds. These reactions were found to produce stereoselectively the trans isomers. Similar reactions of 4′,7-diacetoxyflavan-4-ol 16 afforded the corresponding 4-arylflavans and 4-heteroarylflavans as mixtures of cis/trans isomers.