592-45-0Relevant articles and documents
Su,Colette
, p. 369,373 (1972)
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Kagawa et al.
, p. 1250 (1970)
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Method for synthesizing diene compounds based on aldehyde-ketone condensation reaction
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Paragraph 0185; 0191-0193, (2019/05/08)
The invention provides a method for synthesizing diene compounds based on an aldehyde-ketone condensation reaction. The method comprises the following steps: firstly, under the action of a condensation catalyst, performing a condensation reaction on ketone compounds and aldehyde compounds to obtain condensation products; then, under the action of a reduction catalyst, performing a reduction reaction on the condensation products obtained in the previous step to obtain reduction products; under the action of a catalyst, performing a dehydration reaction on the reduction products obtained in theprevious step to obtain the diene compounds. According to the method, ketone, aldehyde as well as homologues of ketone and aldehyde which are cheap and easy to obtain can be used as raw materials forsynthesizing the diene compounds such as butadiene, piperylene as well as homologues of butadiene and piperylene, experimental conditions are mild, the operation is simple, and a large-scale synthesisprospect is achieved.
Ring Opening of Biomass-Derived Cyclic Ethers to Dienes over Silica/Alumina
Kumbhalkar, Mrunmayi D.,Buchanan, J. Scott,Huber, George W.,Dumesic, James A.
, p. 5248 - 5256 (2017/08/17)
We show that cyclic ethers, such 2-methyltetrahydrofuran (2-MTHF), can undergo dehydration to produce pentadienes over SiO2/Al2O3. The catalyst exhibited reversible deactivation due to coke deposition, with the yield to pentadienes decreasing from 68% to 52% at 623 K over 58 h time on stream. A reaction network for 2-MTHF dehydration was proposed on the basis of the results of space time studies. Pentadienes can be produced directly by a concerted hydride shift and dehydration of carbenium intermediates or indirectly through dehydration of pentanal and pentenol. Reaction kinetics studies were performed at temperatures ranging from 573 to 653 K and 2-MTHF partial pressures from 0.21 to 2.51 kPa. The apparent activation energy barrier for 2-MTHF conversion to pentadienes and the reaction rate order for ring opening were determined to be 74 kJ mol-1 and 0.24, respectively, indicating strong interaction between 2-MTHF and the SiO2/Al2O3 surface. Other solid acids such as γ-Al2O3, H-ZSM-5, and Al-Sn-Beta were found to be active for 2-MTHF dehydration to pentadienes. The rate of ring opening decreased in the order 2,5-dimethyltetrahydrofuran > 2-MTHF > tetrahydropyran > tetrahydrofuran. Over SiO2/Al2O3, the dehydration of 2,5-dimethyltetrahydrofuran resulted in 75% yield to hexadiene isomers. (Figure Presented).
Synthesis and characterization of tridentate schiff base derivative of indenyl lanthanoid chloride tetrahydrofuranate complexes for catalytic applications
Yousaf, Muhammad,Zahoor, Ameer Fawad,Anjum, Anbreen,Bokhari, Tanveer Hussain,Ali, Kulsoom Ghulam,Purveen, Bushra,Naheed, Shazia,Jabbar, Abdul,Ahmad, Hafiz Badaruddin
, p. 518 - 520 (2013/02/22)
Four kinds of novel lanthanocene complexes were synthesized in reasonable yield by the reaction of equimolar quantity of sodium salt of tridentate Schiff base [N-(2-methoxyphenyl)salicylideneimine] with indenyl lanthanoid dichloride tetrahydrofuranate in tetrahydrofuran. All the complexes after purification were characterized by MS and EA, respectively. These complexes isomerized successfully the 1,5- hexadiene into a mixture of products such as 1,4-hexadiene, 2,4-hexadiene,1,3-hexadiene, methylenecyclopentane and methylcyclopentene. Similarly they also proved effective for the polymerization of methylmethacrylate (MMA), 56.45 % yield and high molecular weight (355 × 103).