59951-65-4Relevant articles and documents
Synthesis and properties of chromophore-functionalized monovinylsilsesquioxane derivatives
?ak, Patrycja,Bo?t, Ma?gorzata,Dudziec, Beata,Grzelak, Magdalena,Januszewski, Rafa?,Marciniak, Bronislaw,Marciniec, Bogdan,Rachuta, Karolina
supporting information, p. 7659 - 7664 (2020/06/09)
A facile and efficient Pd-based Suzuki-Miyaura coupling reaction leading to mixed chromophores with styryl fragments, enabling their further application, is presented. We also disclose their use in the formation of monofunctionalized silsesquioxanes with a chromophore group covalently bound to a T8 core that have been prepared via a cross-metathesis reaction. These new materials were studied in terms of their photophysical and also thermal properties.
NOVEL COMPOUND AND ORGANIC ELECTROLUMINESCENT DEVICE COMPRISING THE SAME
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Paragraph 0110-0111; 0115-0116, (2020/05/29)
Organic electroluminescent devices with lowered driving voltages, and enhanced efficiencies and lifetimes are provided.
Annular N-heterocycle double-carbene palladium coordination compound and preparation method and application thereof
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Paragraph 0036; 0037; 0038; 0039; 0040; 0041, (2018/04/26)
The invention discloses an annular N-heterocycle double-carbene palladium coordination compound and a preparation method and application thereof. 1,4-2(N-ethyl-benzimidazole onium methyl)-2,3,5,6-tetramethylbenzene arene salt is used as a precursor of the annular N-heterocycle double-carbene palladium coordination compound. The synthetic annular N-heterocycle double-carbene palladium coordinationcompound is used as a catalyst and used for catalyzing the cross-coupling reaction of carbon-carbon bonds. The preparation method of the annular N-heterocycle double-carbene palladium coordination compound comprises the steps that under nitrogen protection, 1,4-2(N-ethyl-benzimidazole onium methyl)-2,3,5,6-tetramethylbenzene arene salt and metal compounds are added to a reaction vessel according to a molar ratio of 1:(2-5), an organic solvent is added to the mixture, then reaction is conducted for 12-24 hours under the temperature of 0-100 DEG C, the mixture is filtered and subjected to etherdiffusion, and the annular N-heterocycle double-carbene palladium coordination compound is obtained. The prepared annular N-heterocycle double-carbene palladium coordination compound is mainly appliedto the technical field of catalysts.