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6002-34-2

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6002-34-2 Usage

Uses

Different sources of media describe the Uses of 6002-34-2 differently. You can refer to the following data:
1. New family of Ph2(t-Bu)P phosphines for efficient Silyl-Heck transformations.
2. Catalyst for:Nickel/Lewis acid-catalyzed carbocyanation of alkynes with acetonitrile or substituted acetonitrilesPalladium catalyzed hydrocarboxylation of acetylene with carbon monoxide to acrylic acid under mild conditionsPalladium to form a catalyst for methoxycarbonylation reactionsRu-catalyzed transfer hydrogenation in reductive coupling of disubstituted allenes with aldehydesStereoselective silylation by dehydrogenative Si-O coupling with Si-stereogenic silanesPhosphine ligand in nickel-catalyzed carbocyanation of alkynesMonodentate P-Donor Ligands (LKB-P)

Check Digit Verification of cas no

The CAS Registry Mumber 6002-34-2 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 6,0,0 and 2 respectively; the second part has 2 digits, 3 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 6002-34:
(6*6)+(5*0)+(4*0)+(3*2)+(2*3)+(1*4)=52
52 % 10 = 2
So 6002-34-2 is a valid CAS Registry Number.
InChI:InChI=1/C16H19P/c1-16(2,3)17(14-10-6-4-7-11-14)15-12-8-5-9-13-15/h4-13H,1-3H3

6002-34-2 Well-known Company Product Price

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  • Aldrich

  • (591688)  tert-Butyldiphenylphosphine  97%

  • 6002-34-2

  • 591688-1G

  • 649.35CNY

  • Detail
  • Aldrich

  • (591688)  tert-Butyldiphenylphosphine  97%

  • 6002-34-2

  • 591688-5G

  • 2,375.10CNY

  • Detail

6002-34-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name tert-Butyldiphenylphosphine

1.2 Other means of identification

Product number -
Other names tert-butyl(diphenyl)phosphane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:6002-34-2 SDS

6002-34-2Relevant articles and documents

A Lewis Base Nucleofugality Parameter, NFB, and Its Application in an Analysis of MIDA-Boronate Hydrolysis Kinetics

García-Domínguez, Andrés,Gonzalez, Jorge A.,Leach, Andrew G.,Lloyd-Jones, Guy C.,Nichol, Gary S.,Taylor, Nicholas P.

supporting information, (2022/01/04)

The kinetics of quinuclidine displacement of BH3 from a wide range of Lewis base borane adducts have been measured. Parameterization of these rates has enabled the development of a nucleofugality scale (NFB), shown to quantify and predict the leaving group ability of a range of other Lewis bases. Additivity observed across a number of series R′3-nRnX (X = P, N; R′ = aryl, alkyl) has allowed the formulation of related substituent parameters (nfPB, nfAB), providing a means of calculating NFB values for a range of Lewis bases that extends far beyond those experimentally derived. The utility of the nucleofugality parameter is explored by the correlation of the substituent parameter nfPB with the hydrolyses rates of a series of alkyl and aryl MIDA boronates under neutral conditions. This has allowed the identification of MIDA boronates with heteroatoms proximal to the reacting center, showing unusual kinetic lability or stability to hydrolysis.

Versatile Visible-Light-Driven Synthesis of Asymmetrical Phosphines and Phosphonium Salts

Arockiam, Percia Beatrice,Lennert, Ulrich,Graf, Christina,Rothfelder, Robin,Scott, Daniel J.,Fischer, Tillmann G.,Zeitler, Kirsten,Wolf, Robert

supporting information, p. 16374 - 16382 (2020/11/03)

Asymmetrically substituted tertiary phosphines and quaternary phosphonium salts are used extensively in applications throughout industry and academia. Despite their significance, classical methods to synthesize such compounds often demand either harsh reaction conditions, prefunctionalization of starting materials, highly sensitive organometallic reagents, or expensive transition-metal catalysts. Mild, practical methods thus remain elusive, despite being of great current interest. Herein, we describe a visible-light-driven method to form these products from secondary and primary phosphines. Using an inexpensive organic photocatalyst and blue-light irradiation, arylphosphines can be both alkylated and arylated using commercially available organohalides. In addition, the same organocatalyst can be used to transform white phosphorus (P4) directly into symmetrical aryl phosphines and phosphonium salts in a single reaction step, which has previously only been possible using precious metal catalysis.

Ambident PCN heterocycles: N- and P-phosphanylation of lithium 1,3-benzazaphospholides

Aluri, Bhaskar R.,Burck, Sebastian,Gudat, Dietrich,Niemeyer, Mark,Holloczki, Oldamur,Nyulaszi, Laszlo,Jones, Peter G.,Heinicke, Joachim

experimental part, p. 12263 - 12272 (2010/06/11)

Synthetic and structural aspects of the phosphanylation of 1,3benzazaphospholides 1L1, ambident benzofused azaphosphacyclopentadienides, are presented. The unusual properties of phospholyl-l,3,2-diazaphospholes inspired us to study the coupling

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