6004-71-3

Basic information

• Product Name: Apoxocamphor
• Synonyms: Apoxocamphor;7,7-dimethyl-2-oxo-norbornane-1-carbaldehyde
• CAS NO: 6004-71-3
• Molecular Formula: C10H14O2
• Molecular Weight: 166.21696
• Mol File: 6004-71-3.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 244.4°C at 760 mmHg
• Flash Point: 89.6°C
• Appearance: /
• Density: 1.175g/cm³
• Vapor Pressure: 0.0305mmHg at 25°C
• Refractive Index: 1.568
• CAS DataBase Reference: Apoxocamphor(CAS DataBase Reference)
• NIST Chemistry Reference: Apoxocamphor(6004-71-3)
• EPA Substance Registry System: Apoxocamphor(6004-71-3)

Safety Data

• Hazardous Substances Data: 6004-71-3(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H14O2/c1-9(2)7-3-4-10(9,6-11)8(12)5-7/h6-7H,3-5H2,1-2H3

Upstream product

• 108-98-5 thiophenol 
• 728880-85-1 7,7-dimethyl-2-oxo-bicyclo[2.2.1]heptane-1-carbothioic acid S-pent-4-ynyl ester 

Relevant articles and documents

Radical Chain Reaction or Benzenethiol with Pentynylthiol Esters: Production of Aldehydes under Stannane/Silane-Free Conditions

The radical chain reaction of benzenethiol with accessible 4-pentynylthiol esters provides a new stannane/silane-free protocol for the production of aromatic and aliphatic aldehydes. The procedure is especially useful for the aryl and primary aldehydes, even in the presence of substituents highly sensitive to reductive conditions, and is also of some utility for the vinylic and secondary ones, The protocol is instead not applicable to the tertiary aldehydes, owing to preferential alkane-forming decarbonylation, although the tertiary ones derived from bridgehead precursors can still be usefully produced.