60059-18-9Relevant articles and documents
RATIO OF POLAR AND RADICAL PROCESSES IN THERMAL TRANSFORMATIONS OF PEROXIDES. I. EFFECT OF THE LENGTH AND BRANCHING OF THE CHAIN IN THE ALKYL SUBSTITUENT AT THE α-CARBON ATOM OF THE ACYL GROUP
Stankevich, A. I.,Zyat'kov, I. P.,Lazareva, A. M.,El'nitskii, A. P.
, p. 1543 - 1548 (2007/10/02)
Acetyl 2-methylpropionyl, acetyl 2-methylbutyryl, acetyl 2-methyloctanoyl, acetyl 2,3-dimethylbutyryl, and acetyl 2,3,3-trimethylbutyryl peroxides are transformed thermally under the investigated experimental conditions with the formation of the corresponding acyl alkyl carbonates and radical products.The ratio of the polar and radical processes is affected by the length and branching of the chain in the hydrocarbon substituent at the α-carbon atom of the acyl group.