60162-33-6 Usage
General Description
Methyl p-methyl-alpha-chloro phenylacetate is a chemical compound with the molecular formula C10H11ClO2. It is a colorless to pale yellow liquid with a strong odor and is often used as an intermediate in the synthesis of pharmaceuticals and agrochemicals. METHYL P-METHYL-ALPHA-CHLORO PHENYLACETATE is commonly used as a building block in the production of various other chemicals and can be found in perfumes, flavorings, and as an artificial fruit flavoring agent. It is also used as a reagent in organic synthesis and as a solvent in various industrial processes. Additionally, methyl p-methyl-alpha-chloro phenylacetate is known to have mild irritant properties and should be handled with care.
Check Digit Verification of cas no
The CAS Registry Mumber 60162-33-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,0,1,6 and 2 respectively; the second part has 2 digits, 3 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 60162-33:
(7*6)+(6*0)+(5*1)+(4*6)+(3*2)+(2*3)+(1*3)=86
86 % 10 = 6
So 60162-33-6 is a valid CAS Registry Number.
InChI:InChI=1/C10H11ClO2/c1-7-3-5-8(6-4-7)9(11)10(12)13-2/h3-6,9H,1-2H3
60162-33-6Relevant articles and documents
Enantioselective α-Chlorination Reactions of in Situ Generated C1 Ammonium Enolates under Base-Free Conditions
Stockhammer, Lotte,Weinzierl, David,B?gl, Thomas,Waser, Mario
, p. 6143 - 6147 (2021/08/18)
The asymmetric α-chlorination of activated aryl acetic acid esters can be carried out with high levels of enantioselectivities utilizing commercially available isothiourea catalysts under base-free conditions. The reaction, which proceeds via the in situ formation of chiral C1 ammonium enolates, is best carried out under cryogenic conditions combined with a direct trapping of the activated α-chlorinated ester derivative to prevent epimerization, thus allowing for enantioselectivities of up to e.r. 99:1.
