6028-46-2Relevant articles and documents
Synthesis, spectral characterization and antibacterial activity of O, O’-dialkyl and alkylene dithiophosphatogold (III)dichloride; crystal structure of [S2POCMe2CMe2O]AuCl2
Elkhaldy, Adnan A. S.,Gaikwad, Dnyaneshwar,Staples, Richard J.,Janen, Afef,Boni, Yannic
, p. 871 - 876 (2019/02/05)
O, O’-Dialkyl and alkylene dithiophosphatogold (III)dichloride complexes of the type [(RO)2PS2]AuCl2 and [S2POGO]AuCl2, where R = Et, nPr, iPr, iBu, Ph, cyclohexyl and cyclopentyl, where G = CMe2CMe2-, have been synthesized in 80-90% yields by reaction of the corresponding acid or sodium salts of the appropriate dithiophosphoric acids in 1:1 ratio with gold (III) chloride in dry dichloromethane at room temperature. The compounds have been characterized by elemental analyses, IR and (1H, l3C, and 31P) NMR. The crystal structure of [S2POCMe2CMe2O]AuCl2, was determined. These new complexes have shown their growth inhibiting potential against various bacterial strains with moderate to good activity.
