60399-53-3

Basic information

• Product Name: (2,6-bis[(di-t-butylphosphino)methyl]phenyl)hydridonickel
• CAS NO: 60399-53-3
• Molecular Weight: 453.251
• Mol File: 60399-53-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2,6-bis[(di-t-butylphosphino)methyl]phenyl)hydridonickel(CAS DataBase Reference)
• NIST Chemistry Reference: (2,6-bis[(di-t-butylphosphino)methyl]phenyl)hydridonickel(60399-53-3)
• EPA Substance Registry System: (2,6-bis[(di-t-butylphosphino)methyl]phenyl)hydridonickel(60399-53-3)

Safety Data

• Hazardous Substances Data: 60399-53-3(Hazardous Substances Data)

Upstream product

• 1277178-87-6 [CpW(CO)₂(μ-κ,C:κ,O-CO)Ni(^tBuPCP)] 
• 1333-74-0 hydrogen 

Relevant articles and documents

Acid-base interaction between transition-metal hydrides: Dihydrogen bonding and dihydrogen evolution

Reaction of the acidic tungsten(II) hydride 2 with the nickel(II) pincer complex 1 in either THF or toluene after an initial dihydrogen bonding (DHB) interaction led to the formation of the Ni-W bimetallic species 3 (see picture). The first example of DHB between two metal hydrides with opposite polarity was analyzed by NMR and IR spectroscopy, X-ray crystallography, and DFT calculations.