607-58-9

Basic information

• Product Name: 1-Benzyloxynaphthalene
• Synonyms: 1-Benzyloxynaphthalene;Benzyl naphthyl ether;Naphthyl benzyl ether;Benzyl alpha-naphthyl ether;1-(PHENYLMETHOXY)NAPHTHALENE;(1-Naphtyl)benzyl ether;1-Naphtylbenzyl ether;1-Naphthyl Benzyl Ether
• CAS NO: 607-58-9
• Molecular Formula: C₁₇H₁₄O
• Molecular Weight: 234.29246
• Product Categories: Aromatics;Intermediates & Fine Chemicals;Pharmaceuticals
• Mol File: 607-58-9.mol
• Article Data: 25

Chemical Properties

• Melting Point: 73.5-74 °C
• Boiling Point: 388.1°C at 760 mmHg
• Flash Point: 156.4°C
• Appearance: /
• Density: 1.125g/cm³
• Vapor Pressure: 7.02E-06mmHg at 25°C
• Refractive Index: 1.642
• Storage Temp.: Sealed in dry,Room Temperature
• Solubility: Chloroform (Slightly), DMSO (Slightly), Ethyl Acetate (Slightly)
• CAS DataBase Reference: 1-Benzyloxynaphthalene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Benzyloxynaphthalene(607-58-9)
• EPA Substance Registry System: 1-Benzyloxynaphthalene(607-58-9)

Safety Data

• Hazardous Substances Data: 607-58-9(Hazardous Substances Data)

Usage

Uses

1-Benzyloxynaphthalene is a naphthyl ether used in studies for the improvement of coal direct liquefaction by steam pretreatment.

InChI:InChI=1/C17H14O/c1-2-7-14(8-3-1)13-18-17-12-6-10-15-9-4-5-11-16(15)17/h1-12H,13H2

Upstream product

• 90-15-3 α-naphthol 
• 3204-68-0 benzyldimethylphenylammonium chloride 
• 100-39-0 benzyl bromide 
• 3019-88-3 sodium naphtholate 
• 124-41-4 sodium methylate 
• 100-44-7 benzyl chloride 
• 135-19-3 β-naphthol 
• 529-34-0 3,4-dihydronaphthalene-1(2H)-one 
• 3433-80-5 1-Bromo-2-bromomethyl-benzene 
• 260783-80-0 N,N,N--trimethyl--1--phenylmethanaminium trifluoromethanesulfonate 
• 86-57-7 1-Nitronaphthalene 
• 100-51-6 benzyl alcohol 
• 90-14-2 1-Iodonaphthalene 
• 90-11-9 1-Bromonaphthalene 

Downstream Products

• 3960-21-2 1,2-di(naphthyl)ethene 
• 135505-52-1 N-(1-Naphthalenyl)-N-phenyl-1-naphthalenemethanamine 
• 92929-51-6 4-nitro-1-naphthyl benzoate 
• 90-15-3 α-naphthol 
• 33490-96-9 1-naphthoxyl radical 
• 103-29-7 1,1'-(1,2-ethanediyl)bisbenzene 
• 108-88-3 toluene 
• 138865-41-5 1-(benzyloxy)-4-bromonaphthalene 
• 642-28-4 phenyl(1-naphthyl)methanol 
• 213455-52-8 4-benzyloxynaphthalene-1-carbaldehyde 
• 830-81-9 1-naphthyl acetate 
• 28178-96-3 4-(phenylmethyl)-1-naphthalenol 
• 20009-25-0 allyl naphthyl ether 

Relevant articles and documents

Aromatic ether compound or the sulfhydryl compound

[Problem] Aromatic ether compounds and aromatic sulfide compound of this new technology to[Solution] In general formula (1a), (1b), (1c) palladium or nickel compound or a phosphine compound represented by the compound comprising a transition metal compound in the presence of a transition metal catalyst, (A1) is represented by compounds having hydroxy carbon C a-OH or (A2) with a compound represented by the sulfhydryl carbon C a-SH, nitro group (- NO2 ) To react with an aromatic nitro compound (B), (A1) to the compound of the aromatic nitro compound (C1) or the reaction product of an aromatic ether compounds (B) hetero coupling (A2) of the compounds of the reaction product of an aromatic sulfide compound of an aromatic nitro compound (C2) generating (B) hetero coupling characterized by comprising the step of, aromatic ether compounds or aromatic sulfide compound. [Drawing] no

Pd-Catalyzed Etherification of Nitroarenes

The Pd-catalyzed etherification of nitroarenes with arenols has been achieved using a new rationally designed ligand. Mechanistic insights were used to design the ligand so that both the oxidative addition and reductive elimination steps of a plausible catalytic cycle were facilitated. The catalytic system established here provides direct access to a range of unsymmetrical diaryl ethers from nitroarenes.

Exploring the Reactivity of α-Lithiated Aryl Benzyl Ethers: Inhibition of the [1,2]-Wittig Rearrangement and the Mechanistic Proposal Revisited

By carefully controlling the reaction temperature, treatment of aryl benzyl ethers with tBuLi selectively leads to α-lithiation, generating stable organolithiums that can be directly trapped with a variety of selected electrophiles, before they can undergo the expected [1,2]-Wittig rearrangement. This rearrangement has been deeply studied, both experimentally and computationally, with aryl α-lithiated benzyl ethers bearing different substituents at the aryl ring. The obtained results support the competence of a concerted anionic intramolecular addition/elimination sequence and a radical dissociation/recombination sequence for explaining the tendency of migration for aryl groups. The more favored rearrangements are found for substrates with electron-poor aryl groups that favor the anionic pathway.