60789-54-0

Basic information

• Product Name: BENZYL 4-BROMOBUTYL ETHER
• Synonyms: 4-BENZYLOXYBUTYL BROMIDE;(4-BROMOBUTOXYMETHYL)BENZENE;BENZYL 4-BROMOBUTYL ETHER;4-Benzyloxy-1-bromobutane;4-Benzyloxybutyl Bromide (4-Bromobutoxymethyl)benzene;Benzene, [(4-broMobutoxy)Methyl]-;4-Bromobutyl phenylmethyl ether;1-((4-bromobutoxy)methyl)benzene
• CAS NO: 60789-54-0
• Molecular Formula: C₁₁H₁₅BrO
• Molecular Weight: 243.14
• Product Categories: Ethers;Organic Building Blocks;Oxygen Compounds
• Mol File: 60789-54-0.mol
• Article Data: 21

Chemical Properties

• Boiling Point: 115 °C / 0.4mmHg
• Flash Point: 113 °C
• Appearance: /
• Density: 1.28
• Vapor Pressure: 0.00439mmHg at 25°C
• Refractive Index: n20/D 1.529(lit.)
• Storage Temp.: Room temperature.
• Solubility: Chloroform (Slightly), Methanol (Slightly)
• CAS DataBase Reference: BENZYL 4-BROMOBUTYL ETHER(CAS DataBase Reference)
• NIST Chemistry Reference: BENZYL 4-BROMOBUTYL ETHER(60789-54-0)
• EPA Substance Registry System: BENZYL 4-BROMOBUTYL ETHER(60789-54-0)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36
• WGK Germany: 3
• Hazardous Substances Data: 60789-54-0(Hazardous Substances Data)

Usage

Uses

Benzyl 4-bromobutyl ether may be used for the synthesis of monodisperse oligo(THF), a supramolecular network structure.

InChI:InChI=1/C11H15BrO/c12-8-4-5-9-13-10-11-6-2-1-3-7-11/h1-3,6-7H,4-5,8-10H2

Upstream product

• 4541-14-4 4-benzyloxy-butan-1-ol 
• 558-13-4 carbon tetrabromide 
• 100-39-0 benzyl bromide 
• 121683-04-3 4-(benzyloxy)butyl methanesulfonate 
• 81518-74-3 1-benzyloxy-4-pentene 
• 110-52-1 1,4-dibromo-butane 
• 100-51-6 benzyl alcohol 
• 33036-62-3 4-Bromo-1-butanol 

Downstream Products

• 60789-55-1 1-benzyloxy-5-hexyne 
• 129512-09-0 methyl 8-benzyloxy-4-methyl-3-oxooctanoate 
• 92485-88-6 3-(4'-benzyloxybutyl)-2-methyl-2-cyclohexene-1-one 
• 80607-13-2 5-Benzyloxy-1-⁽¹³⁾C-pentansaeure 
• 133447-58-2 (-)-(R)-7-Benzyloxy-2-heptanol 
• 70388-33-9 4-benzyloxybut-1-ene 
• 129512-07-8 methyl (2Z)-8-benzyloxy-3-<(diethoxy)phosphoryloxy>-4-methyl-2-octenoate 
• 104948-24-5 4-(Benzyloxy)butyl phenyl sulfone 
• 91477-32-6 5-(Benzyloxy)pentane nitrile 
• 211234-48-9 2-(4-benzyloxybutyl)cyclopentanone 
• 181300-46-9 2-(4-benzyloxybutyl)cyclohexanone 
• 454439-58-8 ethyl 2-[4-(benzyloxy)butyl]acrylate 
• 101747-16-4 (4-(benzyloxy)butyl)benzene 
• 636586-67-9 (Z)-(6R,7S,8S)-1,6,7,8-Tetrakis-benzyloxy-undec-9-en-5-ol 

Relevant articles and documents

Dendrimer-based transient supramolecular networks

Association of a 16-fold excess of a monodisperse telechelic oligo(THF) (Mw = 1270 g/mol) containing two end groups that selectively bind to the 32 binding sites of a fifth generation dendritic host (Mw = 18511 g/mol and radius R h = 2.4 nm) re

A Protocol for Direct Stereospecific Amination of Primary, Secondary, and Tertiary Alkylboronic Esters

The direct, stereospecific amination of alkylboronic and borinic esters can be conducted by treatment of the organoboron compound with methoxyamine and potassium tert -butoxide. In addition to being stereospecific, this process also enables the direct amination of tertiary boronic esters in an efficient fashion.

Light-mediated deoxygenation of alcohols with a dimeric gold catalyst

A new protocol for the reductive deoxygenation of primary alcohols was explored. This photo-mediated method combines a novel approach to bromination of alcohols merged with the powerful reducing capability of [Au2(dppm)2]Cl2 [dppm = 1,1-bis(diphenylphosphino)methane] as a photoredox catalyst. The highly efficient methods discussed are marked by the use of UVA light-emitting diodes, which have significantly reduced reaction times and lowered setup cost.